Low-Temperature Carbonization of Active Centers is the Reason of Pd/C Catalysts Deactivation Full article
| Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2021, Volume: 62, Number: 1, Pages: 163–170 Pages count : 8 DOI: 10.1134/S0022476621010194 | ||
| Tags | Pd nanoparticles, TEM, XRD, RFES, Pd/C, debenzylation, catalyst active centers, deactivation | ||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0001 |
| 2 | Federal Agency for Scientific Organizations | 0303-2016-0004 |
| 3 | Russian Foundation for Basic Research | 19-03-00595 |
Abstract:
Physicochemical and catalytic properties of Pd/C catalysts before and after the deactivation as a result of a dimethylbenzylamine debenzylation–acylation reaction are compared. A comprehensive analysis conducted by a number of methods (chemisorption, X-ray photoelectron spectroscopy, electron microscopy, X-ray diffraction) showed that a tenfold loss of the catalyst activity in the reaction conducted in soft conditions (atmospheric H2 pressure, 25 °C) is related to the formation of a nanoscale graphite phase. While this phenomenon is common for high temperature reactions, it is first discovered at low temperatures.
Cite:
Troitskii S.Y.
, Nartova A.V.
, Moroz E.M.
Low-Temperature Carbonization of Active Centers is the Reason of Pd/C Catalysts Deactivation
Journal of Structural Chemistry. 2021. V.62. N1. P.163–170. DOI: 10.1134/S0022476621010194 WOS Scopus РИНЦ AN OpenAlex
Low-Temperature Carbonization of Active Centers is the Reason of Pd/C Catalysts Deactivation
Journal of Structural Chemistry. 2021. V.62. N1. P.163–170. DOI: 10.1134/S0022476621010194 WOS Scopus РИНЦ AN OpenAlex
Original:
Троицкий С.Ю.
, Нартова А.В.
, Мороз Э.М.
Низкотемпературное зауглероживание активных центров - причина дезактивации катализаторов Pd/C
Журнал структурной химии. 2021. Т.62. №1. С.167-175. DOI: 10.26902/jsc_id66759 РИНЦ OpenAlex
Низкотемпературное зауглероживание активных центров - причина дезактивации катализаторов Pd/C
Журнал структурной химии. 2021. Т.62. №1. С.167-175. DOI: 10.26902/jsc_id66759 РИНЦ OpenAlex
Dates:
| Submitted: | Jul 9, 2020 |
| Accepted: | Aug 20, 2020 |
| Published print: | Jan 1, 2021 |
| Published online: | Feb 15, 2021 |
Identifiers:
| Web of science: | WOS:000618238700019 |
| Scopus: | 2-s2.0-85101468571 |
| Elibrary: | 46752900 |
| Chemical Abstracts: | 2021:409506 |
| OpenAlex: | W3130798370 |