Hydrodeboration of Potassium Polyfluoroaryl(fluoro)borates with Alcohols | Sciact - CRIS-system of Boreskov Institute of Catalysis

Hydrodeboration of Potassium Polyfluoroaryl(fluoro)borates with Alcohols Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2014, Volume: 168, Pages: 111-120 Pages count : 10 DOI: 10.1016/j.jfluchem.2014.09.016

Tags

Hydrodeboration, NMR spectroscopy, Pentafluorophenyltrifluoroborate

Authors

Adonin Nicolay Yu. ^1,2 , Shabalin Anton Yu. ¹ , Bardin Vadim V. ^2,3

Affiliations

1	G.K. Boreskov Institute of Catalysis, SB RAS, Acad. Lavrentjev Avenue 5, 630090 Novosibirsk, Russian Federation
2	Novosibirsk State University, Pirogova Street, 2, 630090 Novosibirsk, Russian Federation
3	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, SB RAS, Acad. Lavrentjev Avenue 9, 630090 Novosibirsk, Russian Federation

Potassium polyfluoroaryltrifluoroborates, K[ArFBF3] (ArF = C6F5, HC6F4, MeC6F4, 4-MeOC6F4, 4-indol-1-ylC6F4, 4-imidazol-1-ylC6F4, 4-pyrazol-1-ylC6F4, 2,4,6-C6F3H2 and 4-tetrafluoropyridyl), and K[(C6F5)2BF2] undergo hydrodeboration to ArFH in aliphatic alcohols at elevated temperature. At the same conditions, borates K[3,4,5-C6F3H2BF3], K[4-FC6H4BF3] and K[C6H5BF3] remain intact. The presence of base (Et3N, K2CO3 and NaOMe) retards or prevents conversion of K[C6F5BF3]. Attempted hydrodeboration of K[C6F5BF3] in MeCN failed.

Adonin N.Y. , Shabalin A.Y. , Bardin V.V.
Hydrodeboration of Potassium Polyfluoroaryl(fluoro)borates with Alcohols
Journal of Fluorine Chemistry. 2014. V.168. P.111-120. DOI: 10.1016/j.jfluchem.2014.09.016 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jul 28, 2014
Accepted:	Sep 15, 2014
Published online:	Sep 28, 2014
Published print:	Dec 1, 2014

Web of science:	WOS:000347019300017
Scopus:	2-s2.0-84922635103
Elibrary:	24032405
Chemical Abstracts:	2014:1663475
Chemical Abstracts (print):	161:628878
OpenAlex:	W2069462543

DB	Citing
Web of science	9
Scopus	8
Elibrary	8
OpenAlex	7