Silver Nanoparticles Obtained by Laser Ablation as the Active Component of Ag/SiO2 Catalysts for CO Oxidation | Sciact - CRIS-system of Boreskov Institute of Catalysis

Silver Nanoparticles Obtained by Laser Ablation as the Active Component of Ag/SiO2 Catalysts for CO Oxidation Full article

Journal

Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204

Output data

Year: 2013, Volume: 110, Number: 2, Pages: 343-357 Pages count : 15 DOI: 10.1007/s11144-013-0617-7

Tags

CO oxidation, Laser ablation, Nanoparticles, Silica, Silver, TEM, XPS

Authors

Kibis L.S. ^1,2 , Stonkus O.A. ¹ , Martynova D.O. ³ , Izaak T.I. ³ , Lapin I.N. ⁴ , Svetlichnyi V.A. ⁴ , Slavinskaya E.M. ¹ , Boronin A.I. ^1,2

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Prosp. Akad. Lavrentieva 5, Novosibirsk, Russia
2	Novosibirsk State University, Pirogova Street 2, Novosibirsk, Russia
3	Tomsk State University, Prosp. Lenina 36, Tomsk, Russia
4	Siberian Physical-Technical Institute of the Tomsk State University, Novosobornaya pl. 1, Tomsk, Russia

Funding (1)

Russian Foundation for Basic Research

12-03-90825

Composite systems comprising a macroporous SiO2 support and silver nanoparticles preliminarily prepared by laser ablation in various liquids were synthesized and studied. Investigation of the catalytic properties of the synthesized composite catalysts demonstrated that, irrespective of particle size, non-interacting metallic silver particles in SiO2 matrix are not active toward the low temperature oxidation of CO, their activity appearing only at temperatures above 300 °C. A combination of X-ray photoelectron spectroscopy and transmission electron microscopy allowed revealing that the activation redox treatment (O2-500 °C/H2-200 °C) of such particles in macroporous SiO2 matrix leads to the structures resembling surface silver silicates AgSiOx, which are active in CO oxidation at temperatures above 200 °C.

Kibis L.S. , Stonkus O.A. , Martynova D.O. , Izaak T.I. , Lapin I.N. , Svetlichnyi V.A. , Slavinskaya E.M. , Boronin A.I.
Silver Nanoparticles Obtained by Laser Ablation as the Active Component of Ag/SiO2 Catalysts for CO Oxidation
Reaction Kinetics, Mechanisms and Catalysis. 2013. V.110. N2. P.343-357. DOI: 10.1007/s11144-013-0617-7 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	May 17, 2013
Accepted:	Jul 26, 2013
Published online:	Aug 8, 2013
Published print:	Dec 1, 2013

Web of science:	WOS:000327219200007
Scopus:	2-s2.0-84890942295
Elibrary:	21902071
Chemical Abstracts:	2013:1229297
Chemical Abstracts (print):	160:522427
OpenAlex:	W1982224107

DB	Citing
Web of science	11
Scopus	10
Elibrary	12
OpenAlex	10