Asymmetric Catalysis Using Metal-Organic Frameworks Review
| Journal |
Coordination Chemistry Reviews
ISSN: 0010-8545 , E-ISSN: 1873-3840 |
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| Output data | Year: 2021, Volume: 437, Article number : 213845, Pages count : 37 DOI: 10.1016/j.ccr.2021.213845 | ||||
| Tags | Asymmetric catalysis; Homochirality; Kinetic resolution; Metal–organic frameworks; Post-synthetic modification | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0009 |
| 2 | Ministry of Science and Higher Education of the Russian Federation | 0236-2021-0001 |
Abstract:
To date, porous coordination polymers (metal–organic frameworks, MOFs) have been extensively studied in multiple applications, including the use of homohiral or chirally modified MOFs in stereoselective catalysis. Homochiral MOFs, assembled from enantiopure chiral building blocks, have sufficient chemical robustness, demonstrate chiral recognition capabilities, hold rich possibilities of synthetic modifications in order to introduce catalytically active sites, and, in addition to catalyst-substrate interactions, may impose size and confined-space effects, thus providing additional means of finely tuning the catalytic activity and selectivity. Herein, the progress in the area of asymmetric catalysis using metal–organic frameworks, achieved during the twenty years of investigation, is summarized. © 2021 Elsevier B.V.
Cite:
Dybtsev D.N.
, Bryliakov K.P.
Asymmetric Catalysis Using Metal-Organic Frameworks
Coordination Chemistry Reviews. 2021. V.437. 213845 :1-37. DOI: 10.1016/j.ccr.2021.213845 WOS Scopus РИНЦ ANCAN OpenAlex
Asymmetric Catalysis Using Metal-Organic Frameworks
Coordination Chemistry Reviews. 2021. V.437. 213845 :1-37. DOI: 10.1016/j.ccr.2021.213845 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Dec 19, 2020 |
| Accepted: | Feb 2, 2021 |
| Published online: | Mar 8, 2021 |
| Published print: | Jun 15, 2021 |
Identifiers:
| Web of science: | WOS:000635576500011 |
| Scopus: | 2-s2.0-85102068861 |
| Elibrary: | 46756215 |
| Chemical Abstracts: | 2021:601257 |
| Chemical Abstracts (print): | 174:804319 |
| OpenAlex: | W3133914813 |