Ethenolysis of C5+ Alkenes as a Method for Synthesis of Propylene Full article
| Journal |
Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296 |
||||
|---|---|---|---|---|---|
| Output data | Year: 2017, Volume: 90, Pages: 1893-1899 Pages count : 7 DOI: 10.1134/S1070427217120011 | ||||
| Tags | Re2O7/SiO2-Al2O3 CATALYSTS; WO3/SiO2 CATALYST; METATHESIS; 2-PENTENE; ETHYLENE; GAMMA-Al2O3; 1-HEXENE; MoO3; PERFORMANCES; SiO2-Al2O3 | ||||
| Authors |
|
||||
| Affiliations |
|
Abstract:
Thermodynamic calculations demonstrated that, when any C5+ alkene is subjected to ethenolysis in an excess of ethylene on a catalyst providing the occurrence of a metathesis and positional isomerization, the main reaction product is propylene. The results of the calculations were confirmed experimentally for the cases of ethenolysis of hexene-1 and heptene-1 on Re2O7/SO42-/ZrO2–Al2O3 and Re2O7/B2O3–Al2O3 catalysts.
Cite:
Buluchevskii E.A.
, Saifullina L.F.
, Lavrenov A.V.
, Karpova T.R.
, Glazov N.A.
Ethenolysis of C5+ Alkenes as a Method for Synthesis of Propylene
Russian Journal of Applied Chemistry. 2017. V.90. P.1893-1899. DOI: 10.1134/S1070427217120011 WOS Scopus РИНЦ ANCAN OpenAlex
Ethenolysis of C5+ Alkenes as a Method for Synthesis of Propylene
Russian Journal of Applied Chemistry. 2017. V.90. P.1893-1899. DOI: 10.1134/S1070427217120011 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Булучевский Е.А.
, Сайфулина Л.Ф.
, Лавренов А.В.
, Карпова Т.Р.
, Глазов Н.А.
Этенолиз алкенов С5+ как метод синтеза пропилена
Журнал прикладной химии. 2017. Т.90. №12. С.1560-1566. РИНЦ
Этенолиз алкенов С5+ как метод синтеза пропилена
Журнал прикладной химии. 2017. Т.90. №12. С.1560-1566. РИНЦ
Dates:
| Submitted: | Nov 7, 2017 |
| Published print: | Dec 1, 2017 |
| Published online: | Apr 25, 2018 |
Identifiers:
| Web of science: | WOS:000429566300001 |
| Scopus: | 2-s2.0-85045234365 |
| Elibrary: | 35508914 |
| Chemical Abstracts: | 2018:745623 |
| Chemical Abstracts (print): | 169:53184 |
| OpenAlex: | W2801841205 |