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Removal of 1,2-Dichlorobenzene from Water Emulsion Using Adsorbent-Catalysts and Its Regeneration Научная публикация

Журнал Journal of Hazardous Materials
ISSN: 0304-3894 , E-ISSN: 1873-3336
Вых. Данные Год: 2015, Том: 285, Страницы: 84-93 Страниц : 10 DOI: 10.1016/j.jhazmat.2014.10.017
Ключевые слова Adsorbent catalyst, Adsorption, Emulsion, Hydrodechlorination, Surface chemistry
Авторы Netskina O.V. 1 , Tayban E.S. 1 , Moiseenko A.P. 1,2 , Komova O.V. 1 , Mukha S.A. 1 , Simagina V.I. 1,3
Организации
1 Laboratory of Hydride Investigation, Boreskov Institute of Catalysis SB RAS, Pr. Akademika Lavrentieva 5, Novosibirsk 630090, Russia
2 Department of Chemistry and Chemical Technology, Novosibirsk State Technical University, Pr. Karla Marksa 20, Novosibirsk 630092, Russia
3 Siberian Branch of the Russian Presidential Academy of National Economy and Public Administration, Nizhegorodskaya 6, Novosibirsk 630102, Russia

Информация о финансировании (1)

1 Российский фонд фундаментальных исследований 12-03-31517

Реферат: Purification of emulsions of 1,2-dichlorobenzene (1,2-DCB) by carbon-based adsorbent catalysts has been studied. The cycle of purification includes: (1) adsorption of 1,2-DCB from the aqueous phase and (II) reductive regeneration by hydrodechlorination of the adsorbed 1,2-DCB by molecular hydrogen in the liquid phase. 1,2-DCB adsorption from aqueous solutions has been found to proceed by the mechanism of volume filling of pores. The rate of hydrodechlorination was shown to correlate with the particle size of the active component: the finer the particles, the higher the activity of the adsorbent catalyst. Pd/FAS with an average Pd particle size of 2.8nm was found to be the most efficient catalyst.
Библиографическая ссылка: Netskina O.V. , Tayban E.S. , Moiseenko A.P. , Komova O.V. , Mukha S.A. , Simagina V.I.
Removal of 1,2-Dichlorobenzene from Water Emulsion Using Adsorbent-Catalysts and Its Regeneration
Journal of Hazardous Materials. 2015. V.285. P.84-93. DOI: 10.1016/j.jhazmat.2014.10.017 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex
Даты:
Поступила в редакцию: 15 авг. 2014 г.
Принята к публикации: 4 окт. 2014 г.
Опубликована online: 27 окт. 2014 г.
Опубликована в печати: 1 мар. 2015 г.
Идентификаторы БД:
Web of science: WOS:000349880100011
Scopus: 2-s2.0-84916620660
РИНЦ: 23958871
Chemical Abstracts: 2014:1815876
Chemical Abstracts (print): 162:143034
PMID (PubMed): 25497020
OpenAlex: W2027156815
Цитирование в БД:
БД Цитирований
Web of science 18
Scopus 20
РИНЦ 20
OpenAlex 18
Альметрики: