Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations Full article
| Journal |
Angewandte Chemie - International Edition
ISSN: 1433-7851 , E-ISSN: 1521-3773 |
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| Output data | Year: 2014, Volume: 53, Number: 36, Pages: 9645-9649 Pages count : 5 DOI: 10.1002/anie.201403673 | ||||
| Tags | allyl complexes, ansa-zirconocenes, olefin polymerization, polymerization catalysis, resting states | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | German Research Foundation | Me 1388/9-1 |
| 2 | Russian Foundation for Basic Research | 14-03-91344 |
Abstract:
In a search for the hitherto elusive catalyst resting state(s) of zirconocene-based olefin polymerization catalysts, a combination of UV/Vis and NMR spectrometric methods reveals that polymer-carrying cationic Zr allyl complexes make up about 90 % of the total catalyst concentration. Other catalyst species that take part in the polymerization process have to be generated from this allyl pool into which they appear to relapse rather frequently.
Cite:
Babushkin D.E.
, Panchenko V.N.
, Brintzinger H-H.
Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations
Angewandte Chemie - International Edition. 2014. V.53. N36. P.9645-9649. DOI: 10.1002/anie.201403673 WOS Scopus РИНЦ ANCAN PMID OpenAlex
Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations
Angewandte Chemie - International Edition. 2014. V.53. N36. P.9645-9649. DOI: 10.1002/anie.201403673 WOS Scopus РИНЦ ANCAN PMID OpenAlex
Original:
Babushkin D.E.
, Panchenko V.N.
, Brintzinger H-H.
Allylzirconiumkomplexe als Reaktionsteilnehmer bei der Zirconocen-katalysierten α-Olefinpolymerisation
Angewandte Chemie (German edition). 2014. Т.126. №36. С.9799-9803. DOI: 10.1002/ange.201403673 OpenAlex
Allylzirconiumkomplexe als Reaktionsteilnehmer bei der Zirconocen-katalysierten α-Olefinpolymerisation
Angewandte Chemie (German edition). 2014. Т.126. №36. С.9799-9803. DOI: 10.1002/ange.201403673 OpenAlex
Dates:
| Submitted: | Mar 25, 2014 |
| Published online: | Jul 7, 2014 |
| Published print: | Sep 1, 2014 |
Identifiers:
| Web of science: | WOS:000342677000043 |
| Scopus: | 2-s2.0-84906948464 |
| Elibrary: | 23987760 |
| Chemical Abstracts: | 2014:1114067 |
| Chemical Abstracts (print): | 161:754132 |
| PMID: | 25044470 |
| OpenAlex: | W2163568720 |