Hydrogenation of Ethyl p-Nitrobenzoate on Pd/Sibunit Catalysts Научная публикация
| Журнал |
Solid Fuel Chemistry
ISSN: 0361-5219 , E-ISSN: 1934-8029 |
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| Вых. Данные | Год: 2014, Том: 48, Номер: 6, Страницы: 364-370 Страниц : 7 DOI: 10.3103/S0361521914060068 | ||||||
| Ключевые слова | Palladium; Carbon Support; Solid Fuel Chemistry; Activate Carbon Powder; Specific Catalytic Activity | ||||||
| Авторы |
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| Организации |
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Реферат:
A series of Pd/C catalysts (2–4 wt % Pd) with different particle sizes of the supported metal was prepared under varied conditions of the formation and surface deposition of the polynuclear hydroxo complexes (PHCs) of palladium(II) on powdered Sibunit carbon supports with their subsequent reduction to the metal. It was found that the liquid-phase hydrogenation of ethyl p-nitrobenzoate to anesthesine (benzocaine) on these catalysts is a structurally sensitive process, and the dependence of the activity of catalysts on their dispersity is expressed as an extremal function; in this case, the most effective catalysts had the average Pd particle size of 3–5 nm. It was demonstrated that the degree of catalyst utilization increased with the pH of Pd(II) PHC formation; this fact indicates that egg-shell-type catalysts were formed at high values of pH. The Pd/Sibunit catalysts are promising for use in the pharmaceutical industry for the synthesis of local anesthetics with p-nitrobenzoic acid as an intermediate
Библиографическая ссылка:
Simonov P.A.
, Romanenko A.V.
, Likholobov V.A.
Hydrogenation of Ethyl p-Nitrobenzoate on Pd/Sibunit Catalysts
Solid Fuel Chemistry. 2014. V.48. N6. P.364-370. DOI: 10.3103/S0361521914060068 WOS Scopus РИНЦ CAPlus OpenAlex
Hydrogenation of Ethyl p-Nitrobenzoate on Pd/Sibunit Catalysts
Solid Fuel Chemistry. 2014. V.48. N6. P.364-370. DOI: 10.3103/S0361521914060068 WOS Scopus РИНЦ CAPlus OpenAlex
Оригинальная:
Симонов П.А.
, Романенко А.В.
, Лихолобов В.А.
Гидрирование этилового эфира п-нитробензойной кислоты в анестезин на катализаторах Pd/Cибунит
Химия твердого топлива. 2014. №6. С.40-46. DOI: 10.7868/S002311 7714060061 РИНЦ
Гидрирование этилового эфира п-нитробензойной кислоты в анестезин на катализаторах Pd/Cибунит
Химия твердого топлива. 2014. №6. С.40-46. DOI: 10.7868/S002311 7714060061 РИНЦ
Даты:
| Поступила в редакцию: | 28 мая 2013 г. |
| Опубликована в печати: | 1 нояб. 2014 г. |
| Опубликована online: | 17 дек. 2014 г. |
Идентификаторы БД:
| Web of science: | WOS:000346480100004 |
| Scopus: | 2-s2.0-84919454760 |
| РИНЦ: | 24020643 |
| Chemical Abstracts: | 2014:2165413 |
| OpenAlex: | W2019578042 |