Chemical and Electrochemical Synthesis, Structure and Magnetic Properties of Mono- and Binuclear 3d-Metal Complexes of N-[2-[(hydroxyalkylimino)methyl]phenyl]-4-methylbenzenesulfonamides | Sciact - CRIS-system of Boreskov Institute of Catalysis

Chemical and Electrochemical Synthesis, Structure and Magnetic Properties of Mono- and Binuclear 3d-Metal Complexes of N-[2-[(hydroxyalkylimino)methyl]phenyl]-4-methylbenzenesulfonamides Full article

Journal

Polyhedron
ISSN: 0277-5387

Output data

Year: 2018, Volume: 154, Pages: 123-131 Pages count : 9 DOI: 10.1016/j.poly.2018.07.053

Tags

Azomethines; Complexes; EPR; X-ray absorption spectroscopy; X-ray diffraction

Authors

Burlov A.S. ¹ , Vlasenko V.G. ² , Koshchienko Yu.V. ¹ , Nikolaevskii S.A. ³ , Kiskin M.A. ³ , Minin V.V. ³ , Ugolkova E.A. ³ , Efimov N.N. ³ , Bogomyakov A.S. ⁴ , Kolodina A.A. ¹ , Zubavichus Ya.V. ⁵ , Levchenkov S.I. ⁶ , Garnovskii D.A. ⁶

Affiliations

1	Institute of Physical and Organic Chemistry of Southern, Federal University
2	Institute of Physics of Southern, Federal University
3	N.S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
4	International Tomography Center, SB RAS
5	NRC Kurchatov Institute
6	Southern Scientific Centre of Russian Academy of Sciences

Complexes of Cu(II), Ni(II), Co(II) and Fe(II) ions with N-[2-[(hydroxyalkylimino)methyl]phenyl]-4-methylbenzenesulfonamides containing the (CH2)n-spacer of a variable length (n = 2–6) were synthesized by chemical and electrochemical methods. All the compounds were characterized by C, H and N elemental analysis, IR, EPR and X-ray absorption spectroscopy data. The dimeric structures of the copper complexes with (CH2)n-spacers (n = 2, 3) were determined by the magnetochemical method and by X-ray diffraction analysis for the copper complex with the (CH2)3-spacer.

Burlov A.S. , Vlasenko V.G. , Koshchienko Y.V. , Nikolaevskii S.A. , Kiskin M.A. , Minin V.V. , Ugolkova E.A. , Efimov N.N. , Bogomyakov A.S. , Kolodina A.A. , Zubavichus Y.V. , Levchenkov S.I. , Garnovskii D.A.
Chemical and Electrochemical Synthesis, Structure and Magnetic Properties of Mono- and Binuclear 3d-Metal Complexes of N-[2-[(hydroxyalkylimino)methyl]phenyl]-4-methylbenzenesulfonamides
Polyhedron. 2018. V.154. P.123-131. DOI: 10.1016/j.poly.2018.07.053 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jun 21, 2018
Accepted:	Jul 29, 2018
Published online:	Aug 4, 2018
Published print:	Nov 1, 2018

Web of science:	WOS:000446286300013
Scopus:	2-s2.0-85051407733
Elibrary:	35736632
Chemical Abstracts:	2018:1461558
Chemical Abstracts (print):	169:314132
OpenAlex:	W2887791015

DB	Citing
Web of science	12
Scopus	11
OpenAlex	13