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Ammoniated Salt Based Solid Sorption Thermal Batteries: A Comparative Study Full article

Journal Applied Thermal Engineering
ISSN: 1359-4311 , E-ISSN: 1873-5606
Output data Year: 2021, Volume: 191, Article number : 116875, Pages count : 14 DOI: 10.1016/j.applthermaleng.2021.116875
Tags Ammonia; Halide salt; Heat upgradation; Resorption; Sorption; Thermal battery; Thermal energy storage
Authors Sharma Rakesh 1 , Kumar E.Anil 2 , Dutta Pradip 1 , Murthy S.Srinivasa 1 , Aristov Yu.I. 3 , Tokrev M. 3 , Li T.X. 4 , Wang R.Z. 4
Affiliations
1 Interdisciplinary Centre for Energy Research, Indian Institute of Science, Bangalore, India
2 Department of Mechanical Engineering, Indian Institute of Technology, Tirupati, India
3 Boreskov Institute of Catalysis, Ac. Lavrentiev av. 5, Novosibirsk, Russia
4 Institute of Refrigeration and Cryogenics, Shanghai Jiao Tong University, Shanghai, China

Funding (3)

1 Ministry of Science and Technology of the People's Republic of China 2018YFE0100300
2 Department of Science and Technology BRICS2017-422-REMULFUN
3 Russian Foundation for Basic Research 18-58-80047

Abstract: Gas-solid chemisorption pairs of ammonia and halide salts have an edge over other pairs for advanced thermal energy storage batteries due to their abundance, easy availability, cost effectiveness, high sorption capacity, and wide operating temperature range. In the present work, thermodynamic analyses of thermal battery systems are performed for various ammonia-halide salt pairs using measured sorption characteristics. The stored thermal energy can also be upgraded by forming a combination of suitable halide salts. A maximum gravimetric energy storage density of 1664 kJ kg−1 is observed for MnCl2 based thermal battery. The degree of heat upgradation can be as high as 43 °C in case of MnCl2–CaCl2 based resorption thermal battery. The first law efficiency is observed to be as high as 0.42 for CaCl2 based thermal battery. The decrease in first law efficiency due to parasitic mass is observed to be in the range of 26–37 % and 57–66% for different CaCl2 and MnCl2 thermal batteries, respectively. It is possible to recover the stored thermal energy in the form of simultaneous heating and cooling effects by using specific combination of salts which enhances the overall efficiency. First law efficiency as high as 0.92 can be achieved with a CaCl2–NaBr resorption thermal battery delivering simultaneous cooling and heating effects at 10 and 55 °C, respectively, while storing thermal energy at 100 °C. © 2021 Elsevier Ltd
Cite: Sharma R. , Kumar E.A. , Dutta P. , Murthy S.S. , Aristov Y.I. , Tokrev M. , Li T.X. , Wang R.Z.
Ammoniated Salt Based Solid Sorption Thermal Batteries: A Comparative Study
Applied Thermal Engineering. 2021. V.191. 116875 :1-14. DOI: 10.1016/j.applthermaleng.2021.116875 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: Dec 28, 2020
Accepted: Mar 16, 2021
Published online: Mar 24, 2021
Published print: Jun 5, 2021
Identifiers:
Web of science: WOS:000647658100026
Scopus: 2-s2.0-85103388801
Elibrary: 46763810
Chemical Abstracts: 2021:777813
OpenAlex: W3138666934
Citing:
DB Citing
Scopus 10
Web of science 8
Elibrary 8
OpenAlex 10
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