Development of Composite LaNi0·6Fe0.4O3-δ-based Air Electrodes for Solid Oxide Fuel Cells with a Thin-Film Bilayer Electrolyte | Sciact - CRIS-система Института катализа

Development of Composite LaNi0·6Fe0.4O3-δ-based Air Electrodes for Solid Oxide Fuel Cells with a Thin-Film Bilayer Electrolyte Научная публикация

Журнал

International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487

Вых. Данные

Год: 2021, Том: 46, Номер: 32, Страницы: 16947-16964 Страниц : 18 DOI: 10.1016/j.ijhydene.2021.02.217

Ключевые слова

Collector; Doped Bi2O3; LaNi0.6Fe0.4O3-δ; Polarization resistance; SOFC cathode; SOFC performance

Авторы

Pikalova E. ^1,2 , Bogdanovich N. ¹ , Kolchugin A. ¹ , Shubin K. ¹ , Ermakova L. ³ , Eremeev N. ⁴ , Farlenkov A. ² , Khrustov A. ¹ , Filonova E. ² , Sadykov V. ^4,5

Организации

1	Institute of High Temperature Electrochemistry UB RAS, Yekaterinburg, Russia
2	Ural Federal University, Yekaterinburg, Russia
3	Institute of Solid State Chemistry UB RAS, Yekaterinburg, Russia
4	Federal Research Center Boreskov Institute of Catalysis, Novosibirsk, Russia
5	Novosibirsk State University, Novosibirsk, Russia

Информация о финансировании (2)

1	Российский фонд фундаментальных исследований	20-03-00151 (АААА-А20-120022090045-9)
2	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	0239-2021-0011

In this study the bilayer composite electrodes based on LaNi0.6Fe0.4O3-δ (LNF) electronic conductor and Bi2O3-based electrolytes doped with Er (Bi1.6Er0.4O3, EDB) and Y (Bi1.5Y0.5O3, YDB) have been developed and their performance has been investigated in the dependence on the electrolyte content and sintering conditions. The polarization resistance of the optimized electrodes with electrolyte content of 50 wt % in the functional layer and with the LNF-EDB-CuO collector is in a range of 0.65–1.09 Ω cm2 at 600 °C and 0.10–0.12 Ω cm2 at 700 °C. The polarization characteristics of the Bi-based electrodes are compared with those for the composite electrodes based on LNF and Ce0.8Sm0.2O1.9 (SDC). The developed electrodes have been tested in a SOFC mode in the anode-supported cells with a thin film electrolyte of YSZ/YDC (Y-doped zirconia/ceria). The single cells with such cathodes are shown to have performance characteristics that are several times higher than that for the cell with a standard platinum cathode. This is due to the optimized content and dispersity of the components; high conductivity of ionic and electronic constituents of the composite electrodes; greatly extended triple phase boundary (TPB) of the electrochemical reaction and advanced electrode design with collector providing uniform current distribution. © 2021 Hydrogen Energy Publications LLC

Pikalova E. , Bogdanovich N. , Kolchugin A. , Shubin K. , Ermakova L. , Eremeev N. , Farlenkov A. , Khrustov A. , Filonova E. , Sadykov V.
Development of Composite LaNi0·6Fe0.4O3-δ-based Air Electrodes for Solid Oxide Fuel Cells with a Thin-Film Bilayer Electrolyte
International Journal of Hydrogen Energy. 2021. V.46. N32. P.16947-16964. DOI: 10.1016/j.ijhydene.2021.02.217 WOS Scopus РИНЦ CAPlus OpenAlex

Поступила в редакцию:	11 янв. 2021 г.
Принята к публикации:	27 февр. 2021 г.
Опубликована online:	29 мар. 2021 г.
Опубликована в печати:	10 мая 2021 г.

Web of science:	WOS:000644993100013
Scopus:	2-s2.0-85103407461
РИНЦ:	46763866
Chemical Abstracts:	2021:696910
OpenAlex:	W3149196783

БД	Цитирований
Scopus	32
Web of science	31
РИНЦ	33
OpenAlex	31