SRGO Hydrotreating over Ni-Phosphide Catalysts on Granulated Al2O3 | Sciact - CRIS-система Института катализа

SRGO Hydrotreating over Ni-Phosphide Catalysts on Granulated Al2O3 Научная публикация

Журнал

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Вых. Данные

Год: 2021, Том: 378, Страницы: 24-32 Страниц : 9 DOI: 10.1016/j.cattod.2021.04.001

Ключевые слова

Hydrodenitrogenation; Hydrodesulfurization; Hydroprocessing; Ni phosphide

Авторы

Shamanaev Ivan V. ¹ , Suvorova Anna O. ^1,2 , Gerasimov Evgeny Yu. ¹ , Pakharukova Vera P. ¹ , Panafidin Maxim A. ¹ , Yakovlev Ilya V. ¹ , Bukhtiyarova Galina A. ¹

Организации

1	Boreskov Institute of Catalysis SB RAS, Lavrentiev Ave. 5, 630090, Novosibirsk, Russia
2	Novosibirsk State University, Pirogova St. 2, 630090, Novosibirsk, Russia

Информация о финансировании (3)

1	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	ГЗ-2017-2020
2	Газпромнефть - Московский НПЗ
3	Газпром нефть

Ni-phosphides present a promising alternative to the conventional hydrotreatment NiMo sulfides. The hydrotreatment catalysts are supported on Al2O3 granules, and the similarly Al2O3 supported Ni-phosphide catalysts provide an interesting case for comparison. In this work the Ni-phosphide catalysts supported on Al2O3 granules were prepared using two procedures: 1) temperature-programmed reduction of “phosphite”-type precursor in hydrogen flow (TPR_I catalyst), 2) treatment of Ni nanoparticles with triphenylphosphine solution at elevated temperature (LP catalyst). The catalysts were characterized by ICP-AES chemical analysis, N2 physisorption, XRD, TEM, XPS, 27Al MAS NMR. The Ni2P particles were found in LP samples, while TPR method gives the mixture of Ni12P5 and Ni2P particles and amorphous AlPO4 on the alumina surface. The behavior of granulated Ni phosphide and conventional sulfided NiMo/Al2O3 catalysts was compared in hydroprocessing of straight-run gas oil (SRGO) at 340 °C, 4 MPa, V(H2)/V(feed) - 400 Nm3/m3, LHSV - 1,5 h−1. Hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) activity of nickel phosphide catalysts were shown to be lower in comparison with NiMo/Al2O3. Hydrotreating of S-containing model compounds (DBT, 4-MDBT, 4,6-DMDBT) was carried out over TPR_I catalyst, and a negative effect of dimethyl disulfide (DMDS) and acridin additions on the HDS activity was observed. © 2021 Elsevier B.V.

Shamanaev I.V. , Suvorova A.O. , Gerasimov E.Y. , Pakharukova V.P. , Panafidin M.A. , Yakovlev I.V. , Bukhtiyarova G.A.
SRGO Hydrotreating over Ni-Phosphide Catalysts on Granulated Al2O3
Catalysis Today. 2021. V.378. P.24-32. DOI: 10.1016/j.cattod.2021.04.001 WOS Scopus РИНЦ CAPlus OpenAlex

Поступила в редакцию:	1 авг. 2020 г.
Принята к публикации:	1 апр. 2021 г.
Опубликована online:	9 апр. 2021 г.
Опубликована в печати:	15 окт. 2021 г.

Web of science:	WOS:000687319200004
Scopus:	2-s2.0-85104324874
РИНЦ:	46835388
Chemical Abstracts:	2021:901975
OpenAlex:	W3154749707

БД	Цитирований
Scopus	8
Web of science	7
РИНЦ	6
OpenAlex	8