Catalysts Based on High-Vanadium Solutions of Molybdovanadophosphoric Heteropolyacids: Achievements, Challenges, and Prospects Review
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2021, Volume: 62, Number: 2, Pages: 197-232 Pages count : 36 DOI: 10.1134/s0023158421020129 | ||
| Tags | heteropolyacids, homogeneous catalysis, oxidation, diene synthesis, regeneration | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0005 |
Abstract:
A retrospective review based on the authors’ work is devoted to homogeneous catalytic systems based on aqueous solutions of Mo–V–P heteropolyacids (HPA-x, x is the number of vanadium atoms). These catalytic systems were first proposed for oxidative reactions at Boreskov Institute of Catalysis. The properties of HPA-x solutions, methods for their synthesis, promising processes occurring in their presence, problems related to the use of these solutions, and ways of solving these problems are considered. Prospects for the creation of industrial processes based on modified high-vanadium HPA-x solutions of non-Keggin compositions are shown.
Cite:
Zhizhina E.G.
, Gogin L.L.
, Rodikova Y.A.
, Bukhtiyarov V.I.
Catalysts Based on High-Vanadium Solutions of Molybdovanadophosphoric Heteropolyacids: Achievements, Challenges, and Prospects
Kinetics and Catalysis. 2021. V.62. N2. P.197-232. DOI: 10.1134/s0023158421020129 WOS Scopus РИНЦ AN OpenAlex
Catalysts Based on High-Vanadium Solutions of Molybdovanadophosphoric Heteropolyacids: Achievements, Challenges, and Prospects
Kinetics and Catalysis. 2021. V.62. N2. P.197-232. DOI: 10.1134/s0023158421020129 WOS Scopus РИНЦ AN OpenAlex
Original:
Жижина Е.Г.
, Гогин Л.Л.
, Родикова Ю.А.
, Бухтияров В.И.
Катализаторы на основе высокованадиевых растворов молибдованадофосфорных гетерополикислот: достижения, проблемы, перспективы
Кинетика и катализ. 2021. Т.62. №2. С.135-174. DOI: 10.31857/S045388112102012X РИНЦ OpenAlex
Катализаторы на основе высокованадиевых растворов молибдованадофосфорных гетерополикислот: достижения, проблемы, перспективы
Кинетика и катализ. 2021. Т.62. №2. С.135-174. DOI: 10.31857/S045388112102012X РИНЦ OpenAlex
Dates:
| Submitted: | Nov 16, 2020 |
| Accepted: | Dec 4, 2020 |
| Published print: | Mar 1, 2021 |
| Published online: | Apr 16, 2021 |
Identifiers:
| Web of science: | WOS:000640512300001 |
| Scopus: | 2-s2.0-85104517947 |
| Elibrary: | 46086058 |
| Chemical Abstracts: | 2021:899261 |
| OpenAlex: | W3153617654 |