High Throughput Study of Ionic Liquids in Controlled Environments with FTIR Spectroscopic Imaging | Sciact - CRIS-system of Boreskov Institute of Catalysis

High Throughput Study of Ionic Liquids in Controlled Environments with FTIR Spectroscopic Imaging Full article

Journal

Journal of Molecular Liquids
ISSN: 0167-7322 , E-ISSN: 1873-3166

Output data

Year: 2021, Volume: 337, Article number : 116412, Pages count : 8 DOI: 10.1016/j.molliq.2021.116412

Tags

Ionic liquids, high throughput, ATR-FTIR imaging, FT-IR spectroscopy, water sorption, toluene sorption, interactions

Authors

Chan K.L.Andrew ^1,2 , Shalygin Anton S. ³ , Martyanov Oleg N. ³ , Welton Tom ⁴ , Kazarian Sergei.G. ¹

Affiliations

1	Department of Chemical Engineering, Imperial College London, South Kensington Campus, London SW7 2AZ, United Kingdom
2	Institute of Pharmaceutical Science, King’s College London, SE1 9NH, United Kingdom
3	Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090, Russia
4	Department of Chemistry, Imperial College London, White City Campus, 80 Wood Lane, London W12 0BZ, United Kingdom

Funding (1)

Ministry of Science and Higher Education of the Russian Federation

075-15-2019-1876

The nature of Ni(I) species formed upon the activation of the N,N-α-diimine Ni(II) ethylene polymerization precatalyst LNiIIBr2 (1) with AlMe3 and MMAO has been studied in detail by 1H, 2H NMR, and electron paramagnetic resonance (EPR) spectroscopy (L = 1,4-bis(2,6-diisopropylphenyl)-2,3-dimethyl-1,4-diazabuta-1,3-diene). It has been shown that neutral paramagnetic NMR and EPR active heterobinuclear complexes of types LNiI(μ-Me)(μ-Br)AlR2 and LNiI(μ-Me)2AlR2 (R = Me in the case of AlMe3 and R = Me or iBu in the case of MMAO) predominate in toluene solutions of 1/AlMe3 and 1/MMAO at room temperature. The effect of the cocatalyst/catalyst ratio on the relative concentrations of LNiI(μ-Me)(μ-Br)AlR2 and LNiI(μ-Me)2AlR2 has been studied and their role in ethylene polymerization is discussed.

Chan K.L.A. , Shalygin A.S. , Martyanov O.N. , Welton T. , Kazarian S.G.
High Throughput Study of Ionic Liquids in Controlled Environments with FTIR Spectroscopic Imaging
Journal of Molecular Liquids. 2021. V.337. 116412 :1-8. DOI: 10.1016/j.molliq.2021.116412 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Mar 31, 2021
Accepted:	May 3, 2021
Published online:	May 5, 2021
Published print:	Sep 1, 2021

Web of science:	WOS:000681039600059
Scopus:	2-s2.0-85106210811
Elibrary:	46071909
Chemical Abstracts:	2021:1114572
OpenAlex:	W3159787539

DB	Citing
Scopus	9
Elibrary	9
Web of science	8
OpenAlex	10