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Redox Reactions between Acetonitrile and Nitrogen Dioxide in the Interlayer Space of Fluorinated Graphite Matrices Научная публикация

Журнал PCCP: Physical Chemistry Chemical Physics
ISSN: 1463-9076 , E-ISSN: 1463-9084
Вых. Данные Год: 2021, Том: 23, Номер: 17, Страницы: 10580-10590 Страниц : 11 DOI: 10.1039/d0cp06412b
Ключевые слова Acetonitrile; Fluorination; Graphite; Halogenation; Intercalation; Intercalation compounds; Nitrogen oxides
Авторы Pinakov D.V. 1 , Makotchenko V.G. 1 , Semushkina G.I. 1 , Chekhova G.N. 1 , Prosvirin I.P. 2 , Asanov I.P. 1 , Fedoseeva Yu.V. 1 , Makarova A.A. 3 , Shubin Yu.V. 1 , Okotrub A.V. 1 , Bulusheva L.G. 1
Организации
1 Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russia
2 Boreskov Institute of Catalysis SB RAS, 5 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russia
3 Physikalische Chemie, Institut für Chemie und Biochemie, Freie Universität Berlin, 14195 Berlin, Germany

Информация о финансировании (2)

1 Federal Ministry of Education and Research 05K19KER
2 Российский фонд фундаментальных исследований 18-29-19073 (АААА-А19-119011090049-5)

Реферат: The interlayer space of 2D materials can be a slit reactor where transformations not typical for the gas phase occur. We report redox reactions involving acetonitrile and nitrogen oxide guests in galleries of fluorinated graphite. Fluorinated graphite intercalation compounds with acetonitrile are treated with dinitrogen tetraoxide and the synthesis products are studied by a set of experimental methods. Data analysis reveals that N2O4 dissociates in fluorinated graphite matrices to form nitrogen-containing species NO3, NO2, NO, and N2. The interaction of NO3 with acetonitrile yields HNO3, which predominates as a guest in the synthesis products independently of the fluorination degree of the matrix. This reaction is accompanied by the removal of fluorine atoms weakly bonded to the graphite layers, leading to partial defluorination of the matrices. Our work demonstrates the possibility of using fluorinated graphite as a test nanoreactor whose dimension can be controlled by fluorination of the layers.
Библиографическая ссылка: Pinakov D.V. , Makotchenko V.G. , Semushkina G.I. , Chekhova G.N. , Prosvirin I.P. , Asanov I.P. , Fedoseeva Y.V. , Makarova A.A. , Shubin Y.V. , Okotrub A.V. , Bulusheva L.G.
Redox Reactions between Acetonitrile and Nitrogen Dioxide in the Interlayer Space of Fluorinated Graphite Matrices
PCCP: Physical Chemistry Chemical Physics. 2021. V.23. N17. P.10580-10590. DOI: 10.1039/d0cp06412b WOS Scopus РИНЦ CAPlus PMID OpenAlex
Даты:
Поступила в редакцию: 11 дек. 2020 г.
Принята к публикации: 2 апр. 2021 г.
Опубликована online: 3 апр. 2021 г.
Опубликована в печати: 7 мая 2021 г.
Идентификаторы БД:
Web of science: WOS:000644391600001
Scopus: 2-s2.0-85105673673
РИНЦ: 46053094
Chemical Abstracts: 2021:797560
PMID (PubMed): 33903859
OpenAlex: W3141440538
Цитирование в БД:
БД Цитирований
Web of science 8
Scopus 9
РИНЦ 8
OpenAlex 9
Альметрики: