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Ultrahigh-Energy-Density Sorption Thermal Battery Enabled by Graphene Aerogel-Based Composite Sorbents for Thermal Energy Harvesting from Air Full article

Journal ACS Energy Letters
, E-ISSN: 2380-8195
Output data Year: 2021, Volume: 6, Number: 5, Pages: 1795-1802 Pages count : 8 DOI: 10.1021/acsenergylett.1c00284
Tags METAL-ORGANIC FRAMEWORK; STORAGE; WATER; ADSORPTION; SALT
Authors Yan Taisen 1 , Li Tingxian 1 , Xu Jiaxing 1 , Chao Jingwei 1 , Wang Ruzhu 1 , Aristov Yuri I. 2 , Gordeeva Larisa G. 2 , Dutta Pradip 3 , Murthy S.Srinivasa 4
Affiliations
1 Research Center of Solar Power & Refrigeration, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
2 Boreskov Institute of Catalysis, Russian Academy of Sciences, Novosibirsk 630090, Russia
3 Department of Mechanical Engineering, Indian Institute of Science, Bangalore 560012, India
4 Interdisciplinary Centre for Energy Research, Indian Institute of Science, Bangalore 560012, India

Funding (3)

1 Ministry of Science and Technology of the People's Republic of China 2018YFE0100300
2 Russian Foundation for Basic Research 18-58-80047
3 Department of Science and Technology BRICS2017-422

Abstract: Sorption-based thermal storage has drawn considerable attention for sustainable and cost-effective thermal management and energy storage. However, the low sorption capacity of sorbents is a long-standing challenge for achieving high-energy-density sorption-based thermal storage. Herein, we demonstrate an ultrahigh-energy/power-density sorption thermal battery (STB) enabled by graphene aerogel (GA)-based composite sorbents for efficient thermal harvesting and storage with record performance. Scalable GA-based composite sorbents with high salt loading are synthesized by confined calcium chloride inside a GA matrix (CaCl2@GA), showing fast sorption kinetics and a large sorption capacity up to 2.89 g·g–1 contributed by the GA matrix and chemisorption–deliquescence–absorption of CaCl2. The STB realizes thermal charging–discharging via the multistep water desorption–sorption of CaCl2@GA sorbent with the humidity from air. Importantly, the lab-scale STB exhibits record energy density of 1580 Wh·kg–1 and power density of 815 W·kg–1 for space heating. Our work offers a promising low-carbon route for efficient thermal energy harvesting, storage, and utilization.
Cite: Yan T. , Li T. , Xu J. , Chao J. , Wang R. , Aristov Y.I. , Gordeeva L.G. , Dutta P. , Murthy S.S.
Ultrahigh-Energy-Density Sorption Thermal Battery Enabled by Graphene Aerogel-Based Composite Sorbents for Thermal Energy Harvesting from Air
ACS Energy Letters. 2021. V.6. N5. P.1795-1802. DOI: 10.1021/acsenergylett.1c00284 WOS Scopus РИНЦ AN OpenAlex
Files: Full text from publisher
Dates:
Submitted: Feb 8, 2021
Accepted: Apr 8, 2021
Published online: Apr 14, 2021
Published print: May 14, 2021
Identifiers:
Web of science: WOS:000651810400016
Scopus: 2-s2.0-85105100361
Elibrary: 46034320
Chemical Abstracts: 2021:860302
OpenAlex: W3153344058
Citing:
DB Citing
Scopus 102
Web of science 97
Elibrary 87
OpenAlex 103
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