Ultrahigh-Energy-Density Sorption Thermal Battery Enabled by Graphene Aerogel-Based Composite Sorbents for Thermal Energy Harvesting from Air | Sciact - CRIS-system of Boreskov Institute of Catalysis

Ultrahigh-Energy-Density Sorption Thermal Battery Enabled by Graphene Aerogel-Based Composite Sorbents for Thermal Energy Harvesting from Air Full article

Journal

ACS Energy Letters
, E-ISSN: 2380-8195

Output data

Year: 2021, Volume: 6, Number: 5, Pages: 1795-1802 Pages count : 8 DOI: 10.1021/acsenergylett.1c00284

Tags

METAL-ORGANIC FRAMEWORK; STORAGE; WATER; ADSORPTION; SALT

Authors

Yan Taisen ¹ , Li Tingxian ¹ , Xu Jiaxing ¹ , Chao Jingwei ¹ , Wang Ruzhu ¹ , Aristov Yuri I. ² , Gordeeva Larisa G. ² , Dutta Pradip ³ , Murthy S.Srinivasa ⁴

Affiliations

1	Research Center of Solar Power & Refrigeration, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
2	Boreskov Institute of Catalysis, Russian Academy of Sciences, Novosibirsk 630090, Russia
3	Department of Mechanical Engineering, Indian Institute of Science, Bangalore 560012, India
4	Interdisciplinary Centre for Energy Research, Indian Institute of Science, Bangalore 560012, India

Funding (3)

1	Ministry of Science and Technology of the People's Republic of China	2018YFE0100300
2	Russian Foundation for Basic Research	18-58-80047
3	Department of Science and Technology	BRICS2017-422

Sorption-based thermal storage has drawn considerable attention for sustainable and cost-effective thermal management and energy storage. However, the low sorption capacity of sorbents is a long-standing challenge for achieving high-energy-density sorption-based thermal storage. Herein, we demonstrate an ultrahigh-energy/power-density sorption thermal battery (STB) enabled by graphene aerogel (GA)-based composite sorbents for efficient thermal harvesting and storage with record performance. Scalable GA-based composite sorbents with high salt loading are synthesized by confined calcium chloride inside a GA matrix (CaCl2@GA), showing fast sorption kinetics and a large sorption capacity up to 2.89 g·g–1 contributed by the GA matrix and chemisorption–deliquescence–absorption of CaCl2. The STB realizes thermal charging–discharging via the multistep water desorption–sorption of CaCl2@GA sorbent with the humidity from air. Importantly, the lab-scale STB exhibits record energy density of 1580 Wh·kg–1 and power density of 815 W·kg–1 for space heating. Our work offers a promising low-carbon route for efficient thermal energy harvesting, storage, and utilization.

Yan T. , Li T. , Xu J. , Chao J. , Wang R. , Aristov Y.I. , Gordeeva L.G. , Dutta P. , Murthy S.S.
Ultrahigh-Energy-Density Sorption Thermal Battery Enabled by Graphene Aerogel-Based Composite Sorbents for Thermal Energy Harvesting from Air

ACS Energy Letters. 2021. V.6. N5. P.1795-1802. DOI: 10.1021/acsenergylett.1c00284 WOS Scopus РИНЦ AN OpenAlex

Full text from publisher

Submitted:	Feb 8, 2021
Accepted:	Apr 8, 2021
Published online:	Apr 14, 2021
Published print:	May 14, 2021

Web of science:	WOS:000651810400016
Scopus:	2-s2.0-85105100361
Elibrary:	46034320
Chemical Abstracts:	2021:860302
OpenAlex:	W3153344058

DB	Citing
Scopus	99
Web of science	95
Elibrary	84
OpenAlex	100