Quantum-Chemical Estimation of the Relative Electron-Donor Properties of Azo, Azomethyne, and Phosphazo Compounds in Donor-Acceptor Complexes ArticleGenre_short.SHORT_COMMUNICATION
| Journal |
Theoretical and Experimental Chemistry
ISSN: 0040-5760 , E-ISSN: 1573-935X |
||
|---|---|---|---|
| Output data | Year: 1976, Volume: 12, Number: 3, Pages: 306-308 Pages count : 3 DOI: 10.1007/bf00527133 | ||
| Tags | electron donor azo phosphazo compound; azomethine compound electron donor; donor acceptor complex beryllium fluoride; thermodn beryllium fluoride azo complex; dipole moment beryllium azo complex | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
The relative electron-donor properties of azo, azomethine, and phosphazo compounds were evaluated using the semiempirical method of PPDP/2 by considering hypothetical mols. HN:NH, H2C:NH and H3P:NH, the protonated forms of these mols., and also their donor-acceptor complexes in which the acceptor component is a BeF2 mol. The electron d. crossing over from the donor to the acceptor component of the complex, the dipole moments, the capacity to form complexes with H+ and the stability of such complexes, and the heat of formation of the donor-acceptor complexes are calculated.
Cite:
Kharabaev N.N.
, Kogan V.A.
, Osipov O.A.
, Zakharov I.I.
Quantum-Chemical Estimation of the Relative Electron-Donor Properties of Azo, Azomethyne, and Phosphazo Compounds in Donor-Acceptor Complexes
Theoretical and Experimental Chemistry. 1976. V.12. N3. P.306-308. DOI: 10.1007/bf00527133 Scopus OpenAlex
Quantum-Chemical Estimation of the Relative Electron-Donor Properties of Azo, Azomethyne, and Phosphazo Compounds in Donor-Acceptor Complexes
Theoretical and Experimental Chemistry. 1976. V.12. N3. P.306-308. DOI: 10.1007/bf00527133 Scopus OpenAlex
Original:
Харабаев Н.Н.
, Коган В.А.
, Осипов О.А.
, Захаров И.И.
Квантовохимическая оценка относительных электронодонорных свойств азо-, азометиновых и фосфазосоединений в донорно-акцепторных комплексах
Теоретическая и экспериментальная химия. 1976. Т.12. №3. С.398-401. ANCAN
Квантовохимическая оценка относительных электронодонорных свойств азо-, азометиновых и фосфазосоединений в донорно-акцепторных комплексах
Теоретическая и экспериментальная химия. 1976. Т.12. №3. С.398-401. ANCAN
Dates:
| Submitted: | Apr 19, 1975 |
| Published print: | May 1, 1976 |
Identifiers:
| Scopus: | 2-s2.0-51649170285 |
| OpenAlex: | W2001880917 |
Citing:
Пока нет цитирований