Anomalies of the Electronic Structure and Physical Properties of Rare-Earth Cobaltites Near Spin Crossover Full article
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Journal of Experimental and Theoretical Physics Letters (JETP Letters)
ISSN: 0021-3640 , E-ISSN: 1090-6487 |
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Output data | Year: 2016, Volume: 104, Number: 8, Pages: 588-600 Pages count : 13 DOI: 10.1134/s002136401620011x | ||||
Tags | METAL-INSULATOR-TRANSITION; MAGNETIC-PROPERTIES; NEUTRON-DIFFRACTION; CRYSTAL-STRUCTURE; RCoO3 R; PHASE-TRANSFORMATIONS; PEROVSKITE-TYPE; Co3+ ION; STATE; LaCoO3 | ||||
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Abstract:
The features of the characteristics of LnCoO(3) cobaltites, where Ln is a rare-earth element, are discussed. Both experiment and theory demonstrate that their essentials are related to the low-spin ground state of cobalt ions. The thermally induced occupation of the excited high-spin state gives rise to peaks in the magnetic susceptibility, specific heat, and thermal expansion, as well as to a smooth insulator-metal transition. The analysis is based both on the data from the current literature concerning LaCoO3 and in many aspects on our own studies of GdCoO3 and La1-x Gd (x) CoO3 solid solutions.
Cite:
Dudnikov V.A.
, Orlov Y.S.
, Kazak N.V.
, Platunov M.S.
, Ovchinnikov S.G.
Anomalies of the Electronic Structure and Physical Properties of Rare-Earth Cobaltites Near Spin Crossover
Journal of Experimental and Theoretical Physics Letters (JETP Letters). 2016. V.104. N8. P.588-600. DOI: 10.1134/s002136401620011x WOS Scopus РИНЦ ANCAN OpenAlex
Anomalies of the Electronic Structure and Physical Properties of Rare-Earth Cobaltites Near Spin Crossover
Journal of Experimental and Theoretical Physics Letters (JETP Letters). 2016. V.104. N8. P.588-600. DOI: 10.1134/s002136401620011x WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Дудников В.А.
, Орлов Ю.С.
, Казак Н.В.
, Платунов М.С.
, Овчинников С.Г.
Аномалии электронной структуры и физических свойств редкоземельных кобальтитов в окрестности спинового кроссовера
Письма в Журнал экспериментальной и теоретической физики. 2016. Т.104. №7-8. С.604-616. DOI: 10.7868/S0370274X16200121 РИНЦ
Аномалии электронной структуры и физических свойств редкоземельных кобальтитов в окрестности спинового кроссовера
Письма в Журнал экспериментальной и теоретической физики. 2016. Т.104. №7-8. С.604-616. DOI: 10.7868/S0370274X16200121 РИНЦ
Files:
Full text from publisher
Dates:
Submitted: | Aug 25, 2016 |
Accepted: | Sep 15, 2016 |
Published print: | Oct 1, 2016 |
Published online: | Jan 6, 2017 |
Identifiers:
Web of science: | WOS:000392145200012 |
Scopus: | 2-s2.0-85008517739 |
Elibrary: | 28499296 |
Chemical Abstracts: | 2017:49874 |
Chemical Abstracts (print): | 168:229298 |
OpenAlex: | W2570270391 |