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The Influence of High-Temperature Treatment of the Carbon Support Sibunit and the Content of Ruthenium on the Activity of Ru-Cs/C Catalysts for Ammonia Synthesis Научная публикация

Конференция Oil and Gas Engineering
26-29 февр. 2020 , Омск
Журнал AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616
Вых. Данные Год: 2020, Том: 2285, Номер: 1, Номер статьи : 020004, Страниц : 8 DOI: 10.1063/5.0027083
Ключевые слова GRAPHITIZATION; GRAPHITE; GRAPHENE
Авторы Borisov V.A. 1,2 , Fedotova P.A. 2 , Iost K.N. 1 , Temerev V.L. 1 , Surovikin Y.V. 1,2 , Arbuzov A.B. 1 , Trenikhin M.V. 1,2 , Shlyapin D.A. 1
Организации
1 Center of New Chemical Technologies, Boreskov Institute of Catalysis SB RAS, 54 Neftezavodskaya Str., Omsk 644040, Russian Federation
2 Omsk State Technical University, 11 Mira Pr., Omsk 644050, Russian Federation

Информация о финансировании (1)

1 Российский научный фонд 18-73-00255

Реферат: It is shown that treatment of Sibunit at 2200 °C leads to a full restructuring of the structural and textural parameters of the carbon support. The structure of Sibunit becomes more ordered – according to the XRD, the interplanar distance d002 decreases by 0.005 nm compared to the original Sibunit; according to the Raman spectroscopy, ID/IG decreases from 1.59 to 1.18 and the 2D-line increases significantly. The specific surface area of Sibunit after heat treatment decreases from 303 to 29 m2/g, the total pore volume decreases by 2 times, and the pore diameter increases by 4 times. The dependence of the specific activity on the amount of the active component is extreme, and the maximum for the 1%Ru-3.4%Cs/Sib2200 catalyst and is 1.52 mol NH3/gRu*h.
Библиографическая ссылка: Borisov V.A. , Fedotova P.A. , Iost K.N. , Temerev V.L. , Surovikin Y.V. , Arbuzov A.B. , Trenikhin M.V. , Shlyapin D.A.
The Influence of High-Temperature Treatment of the Carbon Support Sibunit and the Content of Ruthenium on the Activity of Ru-Cs/C Catalysts for Ammonia Synthesis
AIP Conference Proceedings. 2020. V.2285. N1. 020004 :1-8. DOI: 10.1063/5.0027083 WOS Scopus РИНЦ CAPlus OpenAlex ЦНХТ ID
Даты:
Опубликована online: 16 нояб. 2020 г.
Идентификаторы БД:
Web of science: WOS:000646026800063
Scopus: 2-s2.0-85096780393
РИНЦ: 45124436
Chemical Abstracts: 2021:1074837
OpenAlex: W3103991964
ЦНХТ ID: 3214
Цитирование в БД:
БД Цитирований
OpenAlex 1
Альметрики: