Oxidation of Organic Substrates in Two-Phase Liquid Systems in the Presence of Tungsten Peroxo Complexes with the Formation of Carboxylic Acids Full article
| Journal |
Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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| Output data | Year: 2021, Volume: 13, Number: 2, Pages: 111-118 Pages count : 8 DOI: 10.1134/S2070050421020100 | ||
| Tags | phase-transfer oxidative catalysis, carboxylic acids, tungsten peroxo complexes, quaternary ammonium bases | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0008 |
| 2 | Russian Foundation for Basic Research | 19-03-00202 |
Abstract:
A brief review is given for the results obtained by the authors at the Boreskov Institute of Catalysis when studying the processes of hydrogen peroxide oxidation for different organic compounds. Some basic catalytic systems for the synthesis of carboxylic acids as products in high demand by different branches of industry and fine organic synthesis are considered under conditions of phase-transfer catalysis. It is shown that the use of preliminarily synthesized catalytic complexes with general formula Q3{PO4[WO(O2)2]4} improves the process parameters, e.g., to increase the product yield, reduce the period of the reaction, reduce catalyst concentrations, compared to processes in which catalyst precursors are introduced into the reaction medium simultaneously with other reagents, and the active complex forms in situ.
Cite:
Selivanova N.V.
, Berdnikova P.V.
, Pai Z.P.
Oxidation of Organic Substrates in Two-Phase Liquid Systems in the Presence of Tungsten Peroxo Complexes with the Formation of Carboxylic Acids
Catalysis in Industry. 2021. V.13. N2. P.111-118. DOI: 10.1134/S2070050421020100 WOS Scopus РИНЦ OpenAlex
Oxidation of Organic Substrates in Two-Phase Liquid Systems in the Presence of Tungsten Peroxo Complexes with the Formation of Carboxylic Acids
Catalysis in Industry. 2021. V.13. N2. P.111-118. DOI: 10.1134/S2070050421020100 WOS Scopus РИНЦ OpenAlex
Original:
Селиванова Н.В.
, Бердникова П.В.
, Пай З.П.
Окисление органических субстратов в двухфазных жидких системах в присутствии пероксокомплексов вольфрама с получением карбоновых кислот
Катализ в промышленности. 2020. Т.20. №5. С.344-351. DOI: 10.18412/1816-0387-2020-5-344-351RSCI РИНЦ AN OpenAlex
Окисление органических субстратов в двухфазных жидких системах в присутствии пероксокомплексов вольфрама с получением карбоновых кислот
Катализ в промышленности. 2020. Т.20. №5. С.344-351. DOI: 10.18412/1816-0387-2020-5-344-351RSCI РИНЦ AN OpenAlex
Dates:
| Submitted: | Jul 2, 2020 |
| Accepted: | Aug 3, 2020 |
| Published print: | Apr 1, 2021 |
| Published online: | Jul 4, 2021 |
Identifiers:
| Web of science: | WOS:000669208800003 |
| Scopus: | 2-s2.0-85110556184 |
| Elibrary: | 46939868 |
| OpenAlex: | W3186462125 |