Synthesis, Structure, and Photoluminescence of Zn(II) and Cd(II) Complexes with N-[2-(diethylaminoalkyliminomethyl)-phenyl]-4-methylbenzenesulfonamides | Sciact - CRIS-system of Boreskov Institute of Catalysis

Synthesis, Structure, and Photoluminescence of Zn(II) and Cd(II) Complexes with N-[2-(diethylaminoalkyliminomethyl)-phenyl]-4-methylbenzenesulfonamides Full article

Journal

Polyhedron
ISSN: 0277-5387

Output data

Year: 2021, Volume: 208, Article number : 115400, Pages count : 12 DOI: 10.1016/j.poly.2021.115400

Tags

Azomethines; Zinc and Cadmium complexes; UV–Vis spectra; X-ray absorption spectroscopy; Photoluminescence

Authors

Burlov Anatolii S. ¹ , Vlasenko Valery G. ² , Koshchienko Yurii V. ¹ , Milutka Maxim S. ¹ , Garnovskii Dmitrii A. ³ , Kolodina Alexandra A. ¹ , Zubavichus Yan V. ⁴ , Kiskin Mikhail A. ⁵

Affiliations

1	Southern Federal University, Institute of Physical and Organic Chemistry, Stachki ave.194/2, 344090 Rostov-on-Don, Russian Federation
2	Southern Federal University, Institute of Physics, Stachki ave.194, 344090 Rostov-on-Don, Russian Federation
3	Southern Scientific Center of Russian Academy of Sciences, 41 Chekhova str., 344006 Rostov-on-Don, Russian Federation
4	Synchrotron Radiation Facility SKIF, Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Nikolskii pr.1, 630559 Koltsovo, Russian Federation
5	Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii prosp.31, Moscow 117901, Russian Federation

Funding (3)

1	Ministry of Science and Higher Education of the Russian Federation	FENW-2020-0031 (0852-2020-0031)
2	Ministry of Science and Higher Education of the Russian Federation
3	Ministry of Science and Higher Education of the Russian Federation	ГЗ-2021-2023

Zn(II) and Cd(II) complexes based on N-[2-(diethylaminoalkyliminomethyl)-phenyl]-4-methylbenzenesulfonamide (HL) of composition ML2 and MHLCl2 were synthesized. The structures of the complexes were established by elemental analysis, IR, 1H NMR, UV spectroscopy, X-ray absorption spectroscopy (EXAFS), and X-ray crystallography. The complexes demonstrate photoluminescent properties in the blue-violet region of the spectrum with the maxima of the PL bands at 426–448 nm and quantum yields of 0.2–0.34.

Burlov A.S. , Vlasenko V.G. , Koshchienko Y.V. , Milutka M.S. , Garnovskii D.A. , Kolodina A.A. , Zubavichus Y.V. , Kiskin M.A.
Synthesis, Structure, and Photoluminescence of Zn(II) and Cd(II) Complexes with N-[2-(diethylaminoalkyliminomethyl)-phenyl]-4-methylbenzenesulfonamides
Polyhedron. 2021. V.208. 115400 :1-12. DOI: 10.1016/j.poly.2021.115400 WOS Scopus AN OpenAlex publication_identifier_short.sciact_skif_identifier_type

Submitted:	Jun 17, 2021
Accepted:	Jul 26, 2021
Published online:	Jul 30, 2021
Published print:	Nov 1, 2021

Web of science:	WOS:000696897300010
Scopus:	2-s2.0-85111911328
Chemical Abstracts:	2021:1711889
OpenAlex:	W3191579854
publication_identifier.sciact_skif_identifier_type:	488

DB	Citing
Scopus	7
Web of science	7
OpenAlex	9