Decomposition of Formic Acid on Pt/N-Graphene Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2021, Volume: 62, Number: 4, Pages: 518-527 Pages count : 10 DOI: 10.1134/S0023158421040017 | ||
| Tags | formic acid; graphene; hydrogen; nitrogen; platinum | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0010 |
Abstract:
The properties of a new catalytic Pt/N-graphene system in the gas-phase reaction of formic acid decomposition for the production of pure hydrogen were studied. Graphene powders undoped and doped with nitrogen atoms were used as carbon supports. Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), high-resolution transmission electron microscopy (TEM), and the chemisorption of CO were used to characterize the synthesized catalysts. It was found that the activity of the catalysts increased upon graphene doping with nitrogen atoms and with increasing the platinum concentration from 0.2 to 1 wt %; the catalyst selectivity in the test reaction was as high as 96–99%.
Cite:
Chesnokov V.V.
, Lisitsyn A.S.
, Sobolev V.I.
, Gerasimov E.Y.
, Prosvirin I.P.
, Chesalov Y.A.
, Chichkan A.S.
, Podyacheva O.Y.
Decomposition of Formic Acid on Pt/N-Graphene
Kinetics and Catalysis. 2021. V.62. N4. P.518-527. DOI: 10.1134/S0023158421040017 WOS Scopus РИНЦ ANCAN OpenAlex
Decomposition of Formic Acid on Pt/N-Graphene
Kinetics and Catalysis. 2021. V.62. N4. P.518-527. DOI: 10.1134/S0023158421040017 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Чесноков В.В.
, Лисицын А.С.
, Соболев В.И.
, Герасимов Е.Ю.
, Просвирин И.П.
, Чесалов Ю.А.
, Чичкань А.С.
, Подъячева О.Ю.
Pt/N-графен в разложении муравьиной кислоты
Кинетика и катализ. 2021. Т.62. №4. С.472-482. DOI: 10.31857/S0453881121040018 РИНЦ OpenAlex
Pt/N-графен в разложении муравьиной кислоты
Кинетика и катализ. 2021. Т.62. №4. С.472-482. DOI: 10.31857/S0453881121040018 РИНЦ OpenAlex
Dates:
| Submitted: | Feb 4, 2021 |
| Accepted: | Apr 20, 2021 |
| Published print: | Jul 1, 2021 |
| Published online: | Aug 19, 2021 |
Identifiers:
| Web of science: | WOS:000686793400011 |
| Scopus: | 2-s2.0-85113159308 |
| Elibrary: | 46982761 |
| Chemical Abstracts: | 2021:1846291 |
| Chemical Abstracts (print): | 176:240229 |
| OpenAlex: | W3194883732 |