Dissecting the Effects of Water Guest Adsorption and Framework Breathing on the AlO4(OH)2 Centres of Metal–Organic Framework MIL-53 (Al) by Solid State NMR and Structural Analysis Научная публикация
| Журнал |
PCCP: Physical Chemistry Chemical Physics
ISSN: 1463-9076 , E-ISSN: 1463-9084 |
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| Вых. Данные | Год: 2021, Том: 23, Номер: 34, Страницы: 18925-18929 Страниц : 5 DOI: 10.1039/d1cp03060d | ||
| Ключевые слова | XYLENE ISOMERS; DYNAMICS; RATIONALE; LINKER; CO2 | ||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | 0239-2021-0003 |
| 2 | Российский фонд фундаментальных исследований | 18-29-04009 |
Реферат:
The relationship between the adsorption of water on MIL-53 (Al) MOF, the structural phase of MIL-53 (Al), and the quadrupole coupling constant of 27Al framework aluminium atom (QCC) of the MOF AlO4(OH)2 centres (Al-sites) has been investigated by combining solid-state 27Al MAS NMR spectroscopy with XRD analysis and DFT calculations. It is established that 27Al QCC is primarily sensitive to water adsorption to the Al-sites and by a minor extent to the framework contraction/expansion interconversions. We thus conclude that the 27Al MAS NMR method is sensitive enough to differentiate the effects of pore contractions and water adsorption to Al-sites basing on the changes of the QCC value.
Библиографическая ссылка:
Khudozhitkov A.E.
, Arzumanov S.S.
, Toktarev A.V.
, Cherepanova S.V.
, Gabrienko A.A.
, Kolokolov D.I.
, Stepanov A.G.
Dissecting the Effects of Water Guest Adsorption and Framework Breathing on the AlO4(OH)2 Centres of Metal–Organic Framework MIL-53 (Al) by Solid State NMR and Structural Analysis
PCCP: Physical Chemistry Chemical Physics. 2021. V.23. N34. P.18925-18929. DOI: 10.1039/d1cp03060d WOS Scopus РИНЦ OpenAlex CAPlusCA PMID
Dissecting the Effects of Water Guest Adsorption and Framework Breathing on the AlO4(OH)2 Centres of Metal–Organic Framework MIL-53 (Al) by Solid State NMR and Structural Analysis
PCCP: Physical Chemistry Chemical Physics. 2021. V.23. N34. P.18925-18929. DOI: 10.1039/d1cp03060d WOS Scopus РИНЦ OpenAlex CAPlusCA PMID
Даты:
| Поступила в редакцию: | 5 июл. 2021 г. |
| Принята к публикации: | 10 авг. 2021 г. |
| Опубликована online: | 11 авг. 2021 г. |
| Опубликована в печати: | 14 сент. 2021 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000687345500001 |
| ≡ Scopus: | 2-s2.0-85114352078 |
| ≡ РИНЦ: | 47018441 |
| ≡ OpenAlex: | W3187447680 |
| ≡ Chemical Abstracts: | 2021:1755106 |
| ≡ Chemical Abstracts (print): | 176:352051 |
| ≡ PMID (PubMed): | 34612431 |