Heat-Resistant TiO2 Nanocomposites with Anatase Phase as Carriers for Highly Efficient CO Oxidation Catalysts Научная публикация
| Журнал |
Materials Research Bulletin
ISSN: 0025-5408 |
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| Вых. Данные | Год: 2022, Том: 145, Номер статьи : 111538, Страниц : 11 DOI: 10.1016/j.materresbull.2021.111538 | ||
| Ключевые слова | anatase to rutile transition; dopant with ceria, yttria; anatase particle intergrowth; catalyst for CO oxidation | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | 0239-2021-0010 |
Реферат:
Thermally stable nanocomposites TiO2 with anatase structure doped with ceria or yttria have been synthesized by impregnation method with using a special precursor of titania. All dopants used in this research increase the temperature of anatase to rutile transition and stabilize anatase phase up to 900 ◦C. In obtained composites calcined at 300-600 ◦C, microstructural analysis revealed the formation of nanocristalline TiO2 structure consisting of intergrown incoherently 3–8 nm fine anatase particles with the formation of inrerblock boundaries between them. In the region of interblock boundaries the anatase structure is disordered and dopants are localized there in near atomic state. Under the heating at high temperatures, all composites have the rather high surface area and uniform pore diameter. The ceria doped composite was used as support for preparation of 2% Pt/Ce-TiO2 catalyst for CO oxidation. The obtained catalyst demonstrates a high catalytic activity at rather low temperature.
Библиографическая ссылка:
Zenkovets G.A.
, Shutilov A.A.
, Gavrilov V.Y.
Heat-Resistant TiO2 Nanocomposites with Anatase Phase as Carriers for Highly Efficient CO Oxidation Catalysts
Materials Research Bulletin. 2022. V.145. 111538 :1-11. DOI: 10.1016/j.materresbull.2021.111538 WOS Scopus РИНЦ CAPlus OpenAlex
Heat-Resistant TiO2 Nanocomposites with Anatase Phase as Carriers for Highly Efficient CO Oxidation Catalysts
Materials Research Bulletin. 2022. V.145. 111538 :1-11. DOI: 10.1016/j.materresbull.2021.111538 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
| Поступила в редакцию: | 20 апр. 2021 г. |
| Принята к публикации: | 29 авг. 2021 г. |
| Опубликована online: | 1 сент. 2021 г. |
| Опубликована в печати: | 1 янв. 2022 г. |
Идентификаторы БД:
| Web of science: | WOS:000702892100006 |
| Scopus: | 2-s2.0-85114307492 |
| РИНЦ: | 46984243 |
| Chemical Abstracts: | 2021:1967567 |
| OpenAlex: | W3197542013 |