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Synergetic Effect of an Iron Oxide Additive to the Composition of a Support for a Pt/TiO2 Catalyst in the Carbon Monoxide Oxidation Reaction Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2021, Volume: 62, Number: 5, Pages: 621–631 Pages count : 11 DOI: 10.1134/S0023158421050104
Tags TiO2, Fe2O3, solid solution, electronic state of Pt, low-temperature CO oxidation
Authors Shutilov A.A. 1 , Zenkovets G.A. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation 0239-2021-0010

Abstract: The effect of iron oxide additives on the formation of the microstructure of supported 1 wt % Pt/(Fe2O3–TiO2) catalysts, the electronic state of platinum, and the catalytic properties of the catalysts in the CO oxidation reaction has been studied. The synthesized catalyst has exhibited a higher activity than that of a 1 wt % Pt/TiO2 catalyst at identical amounts of platinum in the samples. It has been found that the introduction of iron oxide in an amount of up to 10 wt % leads to the formation of a solid solution of iron ions in titania with an anatase structure. The supporting of platinum has led to a decrease in the particle size and an increase in the content of platinum in the Ptδ+ state. An optimum chemical composition of the catalyst that provides the highest activity in the studied reaction has been determined.
Cite: Shutilov A.A. , Zenkovets G.A.
Synergetic Effect of an Iron Oxide Additive to the Composition of a Support for a Pt/TiO2 Catalyst in the Carbon Monoxide Oxidation Reaction
Kinetics and Catalysis. 2021. V.62. N5. P.621–631. DOI: 10.1134/S0023158421050104 WOS Scopus РИНЦ AN OpenAlex
Original: Шутилов А.А. , Зенковец Г.А.
Синергетический эффект добавки оксида железа в состав носителя Pt/TiO2-катализатора в реакции окисления CO
Кинетика и катализ. 2021. Т.62. №5. С.569-580. DOI: 10.31857/s0453881121050117 РИНЦ OpenAlex
Dates:
Submitted: Dec 29, 2020
Accepted: May 19, 2021
Published print: Sep 1, 2021
Published online: Sep 25, 2021
Identifiers:
Web of science: WOS:000699025100007
Scopus: 2-s2.0-85115672217
Elibrary: 47052126
Chemical Abstracts: 2021:2110657
OpenAlex: W3202547366
Citing: Пока нет цитирований
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