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Theoretical Prediction of the Efficiency of Hydrogen Production via Alkane Dehydrogenation in Catalytic Membrane Reactor Научная публикация

Журнал Hydrogen
ISSN: 2673-4141
Вых. Данные Год: 2021, Том: 2, Номер: 3, Страницы: 362-376 Страниц : 15 DOI: 10.3390/hydrogen2030019
Ключевые слова hydrogen production; alkane dehydrogenation; membrane reactor; porous ceramic membrane; mathematical modeling
Авторы Shelepova Ekaterina V. 1 , Vedyagin Aleksey A. 1
Организации
1 Department of Materials Science and Functional Materials, Boreskov Institute of Catalysis SB RAS, Lavrentieva Ave 5, 630090 Novosibirsk, Russia

Информация о финансировании (1)

1 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) 0239-2021-0010

Реферат: The hydrogen economy is expected to dominate in the nearest future. Therefore, the most hydrogen-containing compounds are considered as potential pure hydrogen sources in order to achieve climate neutrality. On the other hand, alkanes are widely used to produce industrially important monomers via various routes, including dehydrogenation processes. Hydrogen is being produced as a by-product of these processes, so the application of efficient separation of hydrogen from the reaction mixture can give double benefits. Implementation of the dehydrogenation processes in the catalytic membrane reactor is that case. Since the use of dense metal membranes, which possess the highest perm-selectivity towards hydrogen, is complicated in practice, the present research is aimed at the optimization of the porous membrane characteristics. By means of a mathematical modeling approach, the effects of pore diameter on the hydrogen productivity and purity for the cases of ethane and propane dehydrogenation processes were analyzed. The pore size value of 0.45 nm was found to be crucial as far as the diffusion of both the alkane and alkene molecules through the membrane takes place.
Библиографическая ссылка: Shelepova E.V. , Vedyagin A.A.
Theoretical Prediction of the Efficiency of Hydrogen Production via Alkane Dehydrogenation in Catalytic Membrane Reactor
Hydrogen. 2021. V.2. N3. P.362-376. DOI: 10.3390/hydrogen2030019 РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 15 авг. 2021 г.
Опубликована в печати: 1 сент. 2021 г.
Принята к публикации: 3 сент. 2021 г.
Опубликована online: 11 сент. 2021 г.
Идентификаторы БД:
РИНЦ: 47595686
Chemical Abstracts: 2022:846392
Chemical Abstracts (print): 178:344307
OpenAlex: W3200981547
Цитирование в БД:
БД Цитирований
РИНЦ 4
OpenAlex 7
Альметрики: