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Graphitization of Synthetic Diamond Crystals: A Morphological Study Full article

Journal Diamond and Related Materials
ISSN: 0925-9635 , E-ISSN: 1879-0062
Output data Year: 2021, Volume: 118, Article number : 108563, Pages count : 7 DOI: 10.1016/j.diamond.2021.108563
Tags Annealing; Facet; Graphitization; Morphology; Synthetic diamond microcrystals
Authors Bokhonov Boris B. 1 , Dudina Dina V. 1 , Sharafutdinov Marat R. 1
Affiliations
1 Institute of Solid State Chemistry and Mechanochemistry SB RAS, Kutateladze str. 18, Novosibirsk, 630128, Russian Federation

Abstract: In the present work, the morphological and structural evolution occurring upon graphitization of synthetic diamond microcrystals of cuboctahedral shape at 1600 °C during vacuum annealing was studied. The most developed facets of the initial diamond crystals are octahedral {111} and cube {100} facets. It was found that graphitization starts from the vertices and edges of the crystals. The {111} facets were more prone to graphitization than the {100} facets. Annealing of the partially graphitized diamond microcrystals in air helped revealing the orientation relationship of the forming graphite platelets with the parent diamond substrate. The graphite structures forming upon full graphitization of the diamond microcrystals retained the shape of the initial crystals.
Cite: Bokhonov B.B. , Dudina D.V. , Sharafutdinov M.R.
Graphitization of Synthetic Diamond Crystals: A Morphological Study
Diamond and Related Materials. 2021. V.118. 108563 :1-7. DOI: 10.1016/j.diamond.2021.108563 WOS Scopus ANCAN OpenAlex
Dates:
Submitted: Jun 20, 2021
Accepted: Aug 10, 2021
Published online: Aug 13, 2021
Published print: Oct 1, 2021
Identifiers:
Web of science: WOS:000696984200004
Scopus: 2-s2.0-85112753938
Chemical Abstracts: 2021:1845680
Chemical Abstracts (print): 180:253085
OpenAlex: W3194820677
Citing:
DB Citing
Scopus 26
Web of science 25
OpenAlex 27
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