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Effect of Carbon Monoxide on the Oxidation of Propane on Pt Glass Fiber Catalyst Full article

Journal Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555
Output data Year: 2021, Volume: 13, Number: 3, Pages: 239-243 Pages count : 5 DOI: 10.1134/S2070050421030077
Tags deep oxidation of hydrocarbons, platinum, glass fiber, kinetic model of the reaction
Authors Kovalev E.V. 1 , Sadovskaya E.M. 1 , Aver’yanova V.V. 1 , Bal’zhinimaev B.S. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation 0239-2021-0010

Abstract: The deep oxidation of hydrocarbons on platinum catalysts underlies most processes for cleaning gas emissions from industrial enterprises. Since carbon monoxide is usually present in exhaust gases, it is important to study its effect on the kinetics of hydrocarbon oxidation. This work presents results from studying the kinetics of propane oxidation on a platinum glass fiber catalyst with and without CO in the reaction mixture. It is found that CO strongly inhibits the oxidation of propane at low temperatures. The effect of CO changes from negative to positive as the temperature rises. Numerical modeling shows the multidirectionality of the effect can be explained by competition between the adsorption of oxygen, propane, and CO on the active sites of the catalyst.
Cite: Kovalev E.V. , Sadovskaya E.M. , Aver’yanova V.V. , Bal’zhinimaev B.S.
Effect of Carbon Monoxide on the Oxidation of Propane on Pt Glass Fiber Catalyst
Catalysis in Industry. 2021. V.13. N3. P.239-243. DOI: 10.1134/S2070050421030077 WOS Scopus РИНЦ OpenAlex
Original: Ковалев Е.В. , Садовская Е.М. , Аверьянова В.В. , Бальжинимаев Б.С.
Влияние монооксида углерода на окисление пропана на платиновом стекловолокнистом катализаторе
Катализ в промышленности. 2021. Т.21. №1-2. С.41-46. DOI: 10.18412/1816-0387-2021-1-2-41-46 РИНЦ AN OpenAlex
Dates:
Submitted: Dec 1, 2020
Accepted: Jan 28, 2021
Published print: Jul 1, 2021
Published online: Sep 29, 2021
Identifiers:
Web of science: WOS:000701694500004
Scopus: 2-s2.0-85116210848
Elibrary: 47508656
OpenAlex: W3201900182
Citing: Пока нет цитирований
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