Recent Progress in Catalytic Acyloxylation of C(sp3)-H Bonds Review
| Journal |
Applied Organometallic Chemistry
ISSN: 0268-2605 , E-ISSN: 1099-0739 |
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| Output data | Year: 2022, Volume: 36, Number: 3, Article number : e6499, Pages count : 29 DOI: 10.1002/aoc.6499 | ||
| Tags | Acetoxylation, Acyloxylation, C-H bond activation, Mechanism, Oxidation | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0009 |
Abstract:
Herewith, recent progress in the transition metal catalyzed, as well as metal-free and electrochemical selective acyloxylations of C(sp3)-H bonds is surveyed. The corresponding modifications of different substrate types such as amines, amides, oximes, aminoacids, nitrogencontaining heterocycles, olefins, carbonyl compounds, carboxylic acids, acetals etc. are covered, focusing on their synthetic potential. Correlations between the nature of the catalyst, oxidant, additives, conditions, and the acyloxylation regio- and chemoselectivity, are revealed, and available mechanistic details are discussed briefly. The time span of the review is 2015-present time.
Cite:
Antonov A.A.
, Bryliakov K.P.
Recent Progress in Catalytic Acyloxylation of C(sp3)-H Bonds
Applied Organometallic Chemistry. 2022. V.36. N3. e6499 :1-29. DOI: 10.1002/aoc.6499 WOS Scopus РИНЦ AN OpenAlex
Recent Progress in Catalytic Acyloxylation of C(sp3)-H Bonds
Applied Organometallic Chemistry. 2022. V.36. N3. e6499 :1-29. DOI: 10.1002/aoc.6499 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Aug 12, 2021 |
| Accepted: | Oct 9, 2021 |
| Published online: | Jan 5, 2022 |
| Published print: | Mar 1, 2022 |
Identifiers:
| Web of science: | WOS:000738966200001 |
| Scopus: | 2-s2.0-85122290995 |
| Elibrary: | 47892023 |
| Chemical Abstracts: | 2022:52618 |
| OpenAlex: | W4206677010 |