CO2 Hydrogenation to Dimethyl Ether over In2O3 Catalysts Supported on Aluminosilicate Halloysite Nanotubes | Sciact - CRIS-system of Boreskov Institute of Catalysis

CO2 Hydrogenation to Dimethyl Ether over In2O3 Catalysts Supported on Aluminosilicate Halloysite Nanotubes Full article

Journal

Green Processing and Synthesis
ISSN: 2191-9542 , E-ISSN: 2191-9550

Output data

Year: 2021, Volume: 10, Number: 1, Pages: 594-605 Pages count : 12 DOI: 10.1515/gps-2021-0058

Tags

CO2 hydrogenation; dimethyl ether; indium oxide catalysts; halloysite nanotubes; mesoporous aluminosilicates

Authors

Pechenkin Alexey ^1,2 , Potemkin Dmitry ^2,3,4 , Badmaev Sukhe ² , Smirnova Ekaterina ¹ , Cherednichenko Kirill ¹ , Vinokurov Vladimir ¹ , Glotov Aleksandr ¹

Affiliations

1	Department of Physical and Colloid Chemistry, Gubkin Russian State University of Oil and Gas, 65 Leninsky prosp., 119991 Moscow, Russia
2	Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
3	Novosibirsk State University, Pirogova St., 2, Novosibirsk 630090, Russia
4	Department of Environmental Engineering, Novosibirsk State Technical University, Karl Marx Pr., 20, 630073, Novosibirsk, Russia

Funding (2)

1	Ministry of Science and Higher Education of the Russian Federation	FSZE-2020-0007 (0768-2020-0007)
2	Russian Foundation for Basic Research	19-33-60056 (АААА-А20-120020490071-0)

This work presents results on CO2 hydrogenation to dimethyl ether (DME) over bifunctional catalysts consisting of In2O3, supported on natural clay halloysite nanotubes (HNT), and HNT modified with Al-MCM-41 silica arrays. The catalysts were characterized by TEM, STEM, EDX-mapping, NH3-TPD, XRD, low-temperature nitrogen adsorption, TPO, and H2-TPR techniques. Catalytic properties of In2O3/HNT and In2O3/Al-MCM-41/HNT in the CO2 hydrogenation to DME were investigated in a fixed-bed continuous flow stainless steel reactor at 10–40 atm, in the temperature range of 200–300°C, at GHSV = 12,000 h−1 and molar ratio of H2:CO2 = 3:1. The best catalyst for CO2 hydrogenation was In2O3/Al-MCM-41/HNT that provided DME production rate 0.15 gDME·(gcat·h)−1 with DME selectivity 53% and at 40 bar, GHSV = 12,000 h−1, and T = 250°C. It was shown that In2O3/Al-MCM-41/HNT exhibited stable operation for at least 40 h on stream.

Pechenkin A. , Potemkin D. , Badmaev S. , Smirnova E. , Cherednichenko K. , Vinokurov V. , Glotov A.
CO2 Hydrogenation to Dimethyl Ether over In2O3 Catalysts Supported on Aluminosilicate Halloysite Nanotubes
Green Processing and Synthesis. 2021. V.10. N1. P.594-605. DOI: 10.1515/gps-2021-0058 WOS Scopus РИНЦ ANCAN OpenAlex

Published print:	Jan 1, 2021
Submitted:	Jun 14, 2021
Accepted:	Sep 1, 2021
Published online:	Oct 6, 2021

Web of science:	WOS:000707544100001
Scopus:	2-s2.0-85117930929
Elibrary:	47517535
Chemical Abstracts:	2022:588777
Chemical Abstracts (print):	179:75901
OpenAlex:	W3205644678

DB	Citing
Web of science	10
Scopus	11
Elibrary	9
OpenAlex	6