Conversion of Natural Feedstocks to Porous Carbons via Carbonization in Fluidized Catalyst Bed Followed by Leaching the Feedstock Mineral Template Phase: A Comparison of Biomass and Sedimentary Raw Materials | Sciact - CRIS-система Института катализа

Conversion of Natural Feedstocks to Porous Carbons via Carbonization in Fluidized Catalyst Bed Followed by Leaching the Feedstock Mineral Template Phase: A Comparison of Biomass and Sedimentary Raw Materials Научная публикация

Журнал

Fuel Processing Technology
ISSN: 0378-3820

Вых. Данные

Год: 2022, Том: 226, Номер статьи : 107076, Страниц : 11 DOI: 10.1016/j.fuproc.2021.107076

Ключевые слова

Porous carbon; Char; Template; Fluidized catalyst bed; Biomass; Rice husk

Авторы

Yeletsky P.M. ^1,2 , Dubinin Yu.V. ^1,2 , Yazykov N.A. ^1,2 , Tabakaev R.B. ² , Okotrub K.A. ³ , Yakovlev V.A. ¹

Организации

1	Federal Research Center Boreskov Institute of Catalysis SB RAS, Acad. Lavrentiev av., 5, Novosibirsk 630090, Russian Federation
2	School of Energy & Power Engineering, National Research Tomsk Polytechnic University, Lenin av., 30, Tomsk 634050, Russian Federation
3	Institute of Automation and Electrometry, SB RAS, Prosp. Koptyuga 1, Novosibirsk 630090, Russian Federation

Информация о финансировании (2)

1	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	0239-2021-0005
2	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	VIU-REC-192/2020

An idea about porosity development in porous carbons from vegetable biomass due to mineral phase leaching from the carbonized feedstock was investigated. As raw materials, wheat bran and rice husk were used. For comparison, two sedimentary feedstocks (highly-mineralized peat and coal) were also utilized. The raw materials, at the first step, were treated via oxidative carbonization in a fluidized catalyst bed reactor at 465, 550, and 600°С, followed by removal of mineral template phase through acid leaching. It was found that this approach allows for obtaining porous carbons with specific surface area up to 369 m2·g−1 and pore volume of 0.28 cm3·g−1. The materials were characterized by SEM and Raman spectroscopy. It was also discovered that in the case of biomass feedstocks, porosity development via mineral phase removal is more effective, while for the peat the increase in texture characteristics is poor, and for the coal – texture properties of porous carbons remain practically the same. Such a result can be explained by different properties of the mineral template phase of the sedimentary feedstocks, which depend on a mineral component accumulation mechanism.

Yeletsky P.M. , Dubinin Y.V. , Yazykov N.A. , Tabakaev R.B. , Okotrub K.A. , Yakovlev V.A.
Conversion of Natural Feedstocks to Porous Carbons via Carbonization in Fluidized Catalyst Bed Followed by Leaching the Feedstock Mineral Template Phase: A Comparison of Biomass and Sedimentary Raw Materials
Fuel Processing Technology. 2022. V.226. 107076 :1-11. DOI: 10.1016/j.fuproc.2021.107076 WOS Scopus РИНЦ CAPlus OpenAlex

Поступила в редакцию:	8 авг. 2021 г.
Принята к публикации:	23 окт. 2021 г.
Опубликована online:	3 нояб. 2021 г.
Опубликована в печати:	1 февр. 2022 г.

Web of science:	WOS:000717769000003
Scopus:	2-s2.0-85118576752
РИНЦ:	47522378
Chemical Abstracts:	2021:2403005
OpenAlex:	W3208844468

БД	Цитирований
Scopus	14
Web of science	13
РИНЦ	13
OpenAlex	12