Gas Pressure Control of Electric Arc Synthesis of Composite Sn–SnO2–C Nanomaterials | Sciact - CRIS-system of Boreskov Institute of Catalysis

Gas Pressure Control of Electric Arc Synthesis of Composite Sn–SnO2–C Nanomaterials Full article

Journal

Vacuum
ISSN: 0042-207X

Output data

Year: 2022, Volume: 195, Article number : 110694, Pages count : 9 DOI: 10.1016/j.vacuum.2021.110694

Tags

Arc discharge; Carbon; Direct simulation Monte-Carlo; Li-ion battery; Nanoparticles; Tin

Authors

Zaikovskii Alexey ¹ , Yudin Ivan ¹ , Kozlachkov Dmitriy ¹ , Nartova Anna ² , Fedorovskaya Ekaterina ³

Affiliations

1	Laboratory of Rarefied Gases, Kutateladze Institute of Thermophysics SB RAS, 1 Lavrentyev Ave, Novosibirsk, 630090, Russian Federation
2	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 630090, Russian Federation
3	Research Group of Electrochemical Energy Conversion, Department of Chemistry, School of Chemical Engineering, Aalto University, P.O. Box 16100, FI-00076, Finland

Funding (1)

Russian Science Foundation

20-79-00085 (121050400014-8)

It was found that the variation of a buffer gas pressure in the reactor chamber can control the structure of the synthesized materials during electric arc sputtering of composite Sn–C electrodes. The gas dynamic model calculated by the direct simulation Monte Carlo method shows that the buffer gas pressure affects the local parameters of tin and carbon vapor condensation. As a result, Core-shell Sn–SnO2 nanoparticles packed in a carbon matrix with various structural properties have been synthesized. It has been found that an increase in the buffer gas pressure leads both to an increase in the average size of the synthesized nanoparticles and to the formation of a more disordered structure of carbon. In turn, the tin and carbon structure affects the electrochemical characteristics of the synthesized Sn–C composite as anode materials for lithium-ion batteries. © 2021

Zaikovskii A. , Yudin I. , Kozlachkov D. , Nartova A. , Fedorovskaya E.
Gas Pressure Control of Electric Arc Synthesis of Composite Sn–SnO2–C Nanomaterials
Vacuum. 2022. V.195. 110694 :1-9. DOI: 10.1016/j.vacuum.2021.110694 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Sep 7, 2021
Accepted:	Oct 18, 2021
Published online:	Oct 21, 2021
Published print:	Jan 1, 2022

Web of science:	WOS:000732986600004
Scopus:	2-s2.0-85117734688
Elibrary:	47517531
Chemical Abstracts:	2021:2308880
OpenAlex:	W3206140746

DB	Citing
Scopus	7
Web of science	6
Elibrary	9
OpenAlex	8