Thermally Controlled Synthesis of Octahedral Rhenium Clusters with 4,4′-Bipyridine and CN− Apical Ligands Full article
| Journal |
Symmetry
ISSN: 2073-8994 |
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| Output data | Year: 2021, Volume: 13, Number: 11, Article number : 2187, Pages count : 12 DOI: 10.3390/sym13112187 | ||||
| Tags | rhenium cluster; redox-active ligands; crystal structure; electronic structure | ||||
| Authors |
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| Affiliations |
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Funding (4)
| 1 | Ministry of Science and Higher Education of the Russian Federation | FWUZ-2021-0005 (121031700313-8) |
| 2 | Russian Foundation for Basic Research | 20-33-70112 (АААА-А20-120013090064-8) |
| 3 | Russian Science Foundation | 19-73-20196 (АААА-А19-119031890079-2) |
| 4 | Ministry of Science and Higher Education of the Russian Federation | FWUZ-2021-0001 (121031700321-3) |
Abstract:
The selective preparation, structural and spectroscopic study of two new rhenium cluster complexes trans-[Re6S8(bpy)4(CN)2] and trans-[Re6S8(bpy)2(CN)4]2− (bpy = 4,4′-bipyridine) obtained by reactions of corresponding hexarhenium cyanohalides with molten bpy are reported. The complexes were crystallized as solvates, displaying supramolecular structures based on cluster units linked by numerous weak interactions with bpy molecules. The molecular compound trans-[Re6S8(bpy)4(CN)2] (1) is insoluble in water and common organic solvents, while the ionic compound trans-Cs1.7K0.3[Re6S8(bpy)2(CN)4] (2) is somewhat soluble in DMSO, DMF and
N-methylpyrrolidone. The presence of the redox-active ligand bpy leads to the occurrence of multi-electron reduction transitions in a solution of 2 at moderate potential values. The ambidentate
CN− ligand is the secondary functional group, which has potential for the synthesis of coordination polymers based on the new cluster complexes. In addition, both new compounds show a weak red luminescence, which is characteristic of complexes with a {Re6S8}2+ cluster core.
Cite:
Ulantikov A.A.
, Sukhikh T.S.
, Gribov E.N.
, Maltseva N.V.
, Brylev K.A.
, Mironov Y.V.
, Gayfulin Y.M.
Thermally Controlled Synthesis of Octahedral Rhenium Clusters with 4,4′-Bipyridine and CN− Apical Ligands
Symmetry. 2021. V.13. N11. 2187 :1-12. DOI: 10.3390/sym13112187 WOS Scopus РИНЦ AN OpenAlex
Thermally Controlled Synthesis of Octahedral Rhenium Clusters with 4,4′-Bipyridine and CN− Apical Ligands
Symmetry. 2021. V.13. N11. 2187 :1-12. DOI: 10.3390/sym13112187 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Oct 19, 2021 |
| Accepted: | Nov 8, 2021 |
| Published print: | Nov 16, 2021 |
| Published online: | Nov 16, 2021 |
Identifiers:
| Web of science: | WOS:000723774800001 |
| Scopus: | 2-s2.0-85119612210 |
| Elibrary: | 47530167 |
| Chemical Abstracts: | 2022:339076 |
| OpenAlex: | W3212935474 |