Effect of High-Temperature Treatment on the Properties of Carbon Nanotube-Based Petroleum Coke Composite Full article
| Journal |
Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532 |
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| Output data | Year: 2021, Volume: 61, Number: 11, Pages: 1200-1206 Pages count : 7 DOI: 10.1134/s0965544121110177 | ||
| Tags | petroleum coke, carbon nanotubes, coking, electrical resistance, sulfur | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 17-73-30032 |
Abstract:
The study involved a series of experiments on the coking of vacuum residue (VR) and of a mixture of carbon nanotubes (CNTs) and VR in an autoclave at 400–550°C. Using XRD, TEM, and electrical resistivity measurements, the properties of petroleum coke (petcoke) and CNT/petcoke composite were investigated and compared with those after calcination in an inert atmosphere at 1000–1100°C. It was found that the coking of a 2.5% CNT/VR mixture reinforces the petcoke with the CNTs. The CNT/petcoke composite exhibits a slightly higher crystallinity than the petcoke. However, the resistivity of the CNT/petcoke composite was found to be more than an order of magnitude lower than that of the petcoke. After high-temperature (1000–1100°C) calcination, the difference in resistivity between the petcoke and the 2.5% CNT/petcoke composite becomes substantially lower. This is associated with a resistivity drop in the petcoke itself, which approximates the resistivity of the carbon nanotubes. It was also identified that the high-temperature calcination reduces the sulfur content in the CNT/petcoke composite, and this reduction is more dramatic than that for the petroleum coke.
Cite:
Chesnokov V.V.
, Chichkan A.S.
, Parmon V.N.
Effect of High-Temperature Treatment on the Properties of Carbon Nanotube-Based Petroleum Coke Composite
Petroleum Chemistry. 2021. V.61. N11. P.1200-1206. DOI: 10.1134/s0965544121110177 WOS Scopus РИНЦ AN OpenAlex
Effect of High-Temperature Treatment on the Properties of Carbon Nanotube-Based Petroleum Coke Composite
Petroleum Chemistry. 2021. V.61. N11. P.1200-1206. DOI: 10.1134/s0965544121110177 WOS Scopus РИНЦ AN OpenAlex
Original:
Чесноков В.В.
, Чичкань А.С.
, Пармон В.Н.
Влияние высокотемпературных обработок на свойства композита «Углеродные нанотрубки-нефтяной кокс»
Нефтехимия. 2021. Т.61. №6. С.788-795. DOI: 10.31857/s0028242121060046 РИНЦ OpenAlex
Влияние высокотемпературных обработок на свойства композита «Углеродные нанотрубки-нефтяной кокс»
Нефтехимия. 2021. Т.61. №6. С.788-795. DOI: 10.31857/s0028242121060046 РИНЦ OpenAlex
Dates:
| Submitted: | Jul 14, 2021 |
| Accepted: | Oct 18, 2021 |
| Published print: | Nov 1, 2021 |
| Published online: | Dec 2, 2021 |
Identifiers:
| Web of science: | WOS:000725469700004 |
| Scopus: | 2-s2.0-85120405059 |
| Elibrary: | 47534744 |
| Chemical Abstracts: | 2021:2665396 |
| OpenAlex: | W4200418305 |