Preparation and Synchrotron X-Ray Structure of an Apically- and Ribbed-Functionalized Iron(II) Clathrochelate Decorated with Six Methoxyl and Two Carboxyl Terminal Groups | Sciact - CRIS-система Института катализа

Preparation and Synchrotron X-Ray Structure of an Apically- and Ribbed-Functionalized Iron(II) Clathrochelate Decorated with Six Methoxyl and Two Carboxyl Terminal Groups Научная публикация

Журнал

Macroheterocycles (Макрогетероциклы)
ISSN: 1998-9539

Вых. Данные

Год: 2021, Том: 14, Номер: 3, Страницы: 225-230 Страниц : 6 DOI: 10.6060/mhc210843z

Ключевые слова

Macrocycles, cage compounds, clathrochelates, iron complexes, ligand reactivity, synchrotron studies

Авторы

Limarev Ilya P. ^1,2 , Zelinskii Genrikh E. ^1,2 , Vologzhanina Anna V. ² , Zubavichus Yan V. ³ , Voloshin Yan Z. ^1,2

Организации

1	Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 119991 Moscow, Russia
2	Nesmeyanov Institute of the Organoelement Compounds RAS, 119991 Moscow, Russia
3	Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russia

Информация о финансировании (4)

1	Российский фонд фундаментальных исследований	19-33-60047 (АААА-А19-119112690085-1)
2	Российский научный фонд	19-73-00300 (АААА-А19-119112690084-4)
3	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)
4	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)

Octafunctionalized iron(II) cage complex with six equivalent methoxyl-terminated alkylsulfide ribbed fragments and two terminal carboxyl groups in its apical aromatic substituents was obtained using nucleophilic substitution of an appropriate hexachloroclathrochelate precursor with an anionic derivative of mercaptoacetic acid; generated in situ in the presence of triethylamine, followed by the further esterification reaction of thus obtained product with methanol. The obtained diamagnetic cage complex was characterized using elemental analysis, MALDI-TOF mass spectrometry, UV-Vis and 1H NMR spectra, and by the synchrotron single crystal X-ray diffraction experiment as well.

Limarev I.P. , Zelinskii G.E. , Vologzhanina A.V. , Zubavichus Y.V. , Voloshin Y.Z.
Preparation and Synchrotron X-Ray Structure of an Apically- and Ribbed-Functionalized Iron(II) Clathrochelate Decorated with Six Methoxyl and Two Carboxyl Terminal Groups
Macroheterocycles (Макрогетероциклы). 2021. V.14. N3. P.225-230. DOI: 10.6060/mhc210843z WOS Scopus РИНЦ CAPlus OpenAlex

Поступила в редакцию:	25 авг. 2021 г.
Принята к публикации:	21 сент. 2021 г.

Web of science:	WOS:000754733300004
Scopus:	2-s2.0-85124994335
РИНЦ:	48006126
Chemical Abstracts:	2022:1277581
OpenAlex:	W4285073519

БД	Цитирований
Scopus	1
РИНЦ	1
Web of science	1