Pt/Ce0.75Zr0.25O2–x Catalysts for Water Gas Shift Reaction: Morphology and Catalytic Properties Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2021, Volume: 62, Number: 6, Pages: 812-819 Pages count : 8 DOI: 10.1134/S0023158421060057 | ||||
| Tags | ceria–zirconia; hydrogen production; platinum catalyst; water gas shift | ||||
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 21-73-20075 |
Abstract:
Highly dispersed 1.9 wt % Pt/Ce0.75Zr0.25O2 –x and 5 wt % Pt/Ce0.75Zr0.25O2– x catalysts with an average particle size of 0.9 nm were prepared by sorption-hydrolytic precipitation. It was shown that the catalysts are active in the water gas shift reaction in a mixture simulating synthesis gas produced by steam reforming of natural gas. At an initial CO concentration of 10 vol % and a flow rate of 30000 ncm3gcat-1 h–1, outlet CO and CH4 concentrations reach 2.5 and 0.01 vol %, respectively, over 1.9 wt % Pt/Ce0.75Zr0.25O2– x at 325°C and 1.5 and 0.075 vol %, respectively, over 5 wt % Pt/Ce0.75Zr0.25O2– x at 300°С. The observed reaction orders for CO and H2O over 5 wt % Pt/Ce0.75Zr0.25O2– x were found to be close to zero, and the apparent activation energy for both catalysts was 86 kJ/mol. Transmission electron microscopy of the catalysts showed that the narrow size distribution and high dispersion of the supported particles are retained during the reaction. However, some coarsening of Pt particles occurs, the average size increases to 1.4 and 1.6 nm for 1.9 wt % Pt/Ce0.75Zr0.25O2– x and 5 wt % Pt/Ce0.75Zr0.25O2– x, respectively. For the catalysts after the reaction, the metallic Pt surface area values, measured by CO chemisorption and transmission electron microscopy, differ significantly. Most likely, it is caused by the presence of some of the surface Pt atoms in the oxidized state. It was shown that the temperature dependences of the turnover frequency in the water gas shift reaction per the length unit of the metal-support interface, coincide for catalysts 1.9 wt % Pt/Ce0.75Zr0.25O2– x and 5 wt % Pt/Ce0.75Zr0.25O2– x. Based on this, an assumption was made about the leading role of the Pt–Ce0.75Zr0.25O2– x boundary in the catalysis of the water gas shift reaction. © 2021, Pleiades Publishing, Ltd.
Cite:
Gorlova A.M.
, Simonov P.A.
, Stonkus O.A.
, Pakharukova V.P.
, Snytnikov P.V.
, Potemkin D.I.
Pt/Ce0.75Zr0.25O2–x Catalysts for Water Gas Shift Reaction: Morphology and Catalytic Properties
Kinetics and Catalysis. 2021. V.62. N6. P.812-819. DOI: 10.1134/S0023158421060057 WOS Scopus РИНЦ AN OpenAlex
Pt/Ce0.75Zr0.25O2–x Catalysts for Water Gas Shift Reaction: Morphology and Catalytic Properties
Kinetics and Catalysis. 2021. V.62. N6. P.812-819. DOI: 10.1134/S0023158421060057 WOS Scopus РИНЦ AN OpenAlex
Original:
Горлова А.М.
, Симонов П.А.
, Стонкус О.А.
, Пахарукова В.П.
, Снытников П.В.
, Потемкин Д.И.
Pt/Ce0.75Zr0.25O2–x-катализаторы паровой конверсии СО: морфология и каталитические свойства
Кинетика и катализ. 2021. Т.62. №6. С.773-781. DOI: 10.31857/s0453881121060058 РИНЦ OpenAlex
Pt/Ce0.75Zr0.25O2–x-катализаторы паровой конверсии СО: морфология и каталитические свойства
Кинетика и катализ. 2021. Т.62. №6. С.773-781. DOI: 10.31857/s0453881121060058 РИНЦ OpenAlex
Dates:
| Submitted: | Jun 25, 2021 |
| Accepted: | Aug 1, 2021 |
| Published print: | Nov 1, 2021 |
| Published online: | Jan 11, 2022 |
Identifiers:
| Web of science: | WOS:000740995000013 |
| Scopus: | 2-s2.0-85122483166 |
| Elibrary: | 47904048 |
| Chemical Abstracts: | 2022:76417 |
| OpenAlex: | W4206011156 |