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Pt-Fe Nanoalloy: Structure Evolution Study and Catalytic Properties in Water Gas Shift Reaction Научная публикация

Журнал Materials Research Bulletin
ISSN: 0025-5408
Вых. Данные Год: 2022, Том: 149, Номер статьи : 111727, Страниц : 7 DOI: 10.1016/j.materresbull.2022.111727
Ключевые слова Nanoalloy; Catalysis; Water gas shift reaction; Platinum; Hydrogen production
Авторы Gorlova Anna 1,2 , Zadesenets Andrey 3 , Filatov Evgeniy 3 , Simonov Pavel 2 , Korenev Sergey 3 , Stonkus Olga 2 , Sobyanin Vladimir 2 , Snytnikov Pavel 2 , Potemkin Dmitriy 1,2
Организации
1 Novosibirsk State University, Pirogova St., 2, Novosibirsk 630090, Russia
2 Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva, 5, Novosibirsk 630090, Russia
3 Nikolaev Institute of Inorganic Chemistry SB RAS, Pr. Akademika Lavrentieva, 3, Novosibirsk 630090, Russia

Информация о финансировании (3)

1 Российский научный фонд 19-73-00157 (АААА-А19-119090590044-0)
2 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) 0239-2021-0011
3 Российский научный фонд 21-73-20203 (121042600285-5)

Реферат: In the present work we studied the properties of Pt0.5Cu0.5, Pt0.5Fe0.5, Pt0.33Ag0.67, Pt0.6Au0.4 nanoalloys in water gas shift (WGS) reaction for the first time. Cu, Fe, Ag, Au were chosen as modifiers due to the low catalytic activity in undesirable side reactions of carbon oxides methanation. Nanoalloys were synthesized via corresponding double complex salts decomposition, which provided the selective formation of bimetallic nanoparticles. A simulated reformate gas mixture, containing (vol.%) 10 CO, 15 CO2, 30 H2O and 45 H2, was used to evaluate the activity of these systems. Only Pt0.5Fe0.5 nanopowder was active, while Pt-FeOx metal-oxide composite was inert. The positive effect of Pt-Fe alloying on WGS performance was also confirmed for silica supported catalysts. TG and XRD in situ analysis reveal that Pt0.5Fe0.5 is stable toward oxidation under WGS reaction conditions (T < 350°C, reductive atmosphere), while Pt-FeOx undergoes partial reduction but without formation of Pt-Fe alloy nanoparticles.
Библиографическая ссылка: Gorlova A. , Zadesenets A. , Filatov E. , Simonov P. , Korenev S. , Stonkus O. , Sobyanin V. , Snytnikov P. , Potemkin D.
Pt-Fe Nanoalloy: Structure Evolution Study and Catalytic Properties in Water Gas Shift Reaction
Materials Research Bulletin. 2022. V.149. 111727 :1-7. DOI: 10.1016/j.materresbull.2022.111727 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 15 июн. 2021 г.
Принята к публикации: 1 янв. 2022 г.
Опубликована online: 8 янв. 2022 г.
Опубликована в печати: 1 мая 2022 г.
Идентификаторы БД:
Web of science: WOS:000780383700005
Scopus: 2-s2.0-8512283754
РИНЦ: 48142813
Chemical Abstracts: 2022:137246
OpenAlex: W4205815049
Цитирование в БД:
БД Цитирований
РИНЦ 2
Web of science 1
OpenAlex 1
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