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Near-Infrared Photothermal Catalysis for Enhanced Conversion of Carbon Dioxide under Mild Conditions Научная публикация

Журнал ACS Applied Materials and Interfaces
ISSN: 1944-8244 , E-ISSN: 1944-8252
Вых. Данные Год: 2022, Том: 14, Номер: 4, Страницы: 5194–5202 Страниц : 9 DOI: 10.1021/acsami.1c18889
Ключевые слова carbon dioxide fixation; mild condition; near-infrared; photothermal catalysis; polyoxometalate
Авторы Chen Xiaofei 1 , Wei Mingfeng 1 , Yang Aibing 1 , Jiang Fengrui 1 , Li Bao 1 , Kholdeeva Oxana A. 2 , Wu Lixin 1
Организации
1 State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, 130012, China
2 Boreskov Institute of Catalysis, 5, av. Acad. Lavrentiev, Novosibirsk 630090, Russia

Информация о финансировании (3)

1 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) 0239-2021-0009
2 National Natural Science Foundation of China 91961117
3 Jilin University 2017TD-10

Реферат: Enhanced conversion of carbon dioxide (CO2) for cycloaddition with epoxide derivatives is highly desired in organic synthesis and green chemistry, yet it is still a challenge to obtain satisfactory activity under mild reaction conditions of temperature and pressure. For this purpose, an unexploited strategy is proposed here by incorporating near-infrared (NIR) photothermal properties into multicomponent catalysts. Through the electrostatic adsorption of Co- or Ce-substituted polyoxometalate (POM) clusters on the surface of graphene oxide (GO) with covalently grafted polyethyleneimine (PEI), a series of composite catalysts POMs@GO-PEI are prepared. The structural and property characterizations demonstrate the synergistic advantages of the catalysts bearing Lewis acids and bases and local NIR photothermal heating from the GO matrix for dramatically enhanced CO2 cycloaddition. Noticeably, while the turnover frequency increases up to 2718 h-1, the heterogeneous catalysts exhibit photothermal stability and recyclability. With this method, the onsite NIR photothermal transformation becomes extendable to more green reaction processes. https://pubs.acs.org/doi/10.1021/acsami.1c18889.
Библиографическая ссылка: Chen X. , Wei M. , Yang A. , Jiang F. , Li B. , Kholdeeva O.A. , Wu L.
Near-Infrared Photothermal Catalysis for Enhanced Conversion of Carbon Dioxide under Mild Conditions
ACS Applied Materials and Interfaces. 2022. V.14. N4. P.5194–5202. DOI: 10.1021/acsami.1c18889 WOS Scopus РИНЦ CAPlus PMID OpenAlex
Даты:
Поступила в редакцию: 30 сент. 2021 г.
Принята к публикации: 11 янв. 2022 г.
Опубликована online: 24 янв. 2022 г.
Опубликована в печати: 2 февр. 2022 г.
Идентификаторы БД:
Web of science: WOS:000757792300001
Scopus: 2-s2.0-85124056936
РИНЦ: 48148091
Chemical Abstracts: 2022:168872
PMID (PubMed): 35067040
OpenAlex: W4207084371
Цитирование в БД:
БД Цитирований
Scopus 21
Web of science 21
РИНЦ 14
OpenAlex 15
Альметрики: