Nanostructuring of CVD Graphene by High-Energy Heavy Ions | Sciact - CRIS-система Института катализа

Nanostructuring of CVD Graphene by High-Energy Heavy Ions Научная публикация

Журнал

Diamond and Related Materials
ISSN: 0925-9635 , E-ISSN: 1879-0062

Вых. Данные

Год: 2022, Том: 123, Номер статьи : 108880, Страниц : 11 DOI: 10.1016/j.diamond.2022.108880

Ключевые слова

CVD graphene; Defects activity; High-energy ion irradiation; Nanopores; Ultrashort nanotubes

Авторы

Antonova Irina V. ^1,2 , Nebogatikova Nadezhda A. ¹ , Erohin Sergey V. ¹ , Prenas Vladimir A. ¹ , Smovzh Dmitrii V. ^3,4 , Suprun Evgenii A. ⁵ , Volodin Vladimir A. ^1,3 , Olejniczak Andrzej ^6,7 , Sorokin Pavel B. ¹

Организации

1	Rzhanov Institute of Semiconductor Physics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk State Technical University, Novosibirsk, Russia
3	Novosibirsk State University, Novosibirsk, Russia
4	Kutateladze Institute of Thermophysics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
5	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
6	Flerov Laboratory of Nuclear Reactions, Joint Institute for Nuclear Research, Dubna, Russia
7	Faculty of Chemistry, Nicolaus Copernicus University, Torun, Poland

Информация о финансировании (1)

Российский научный фонд

19-72-10046

In this study, CVD graphene with a typical set of structural features (domains, folds and blisters) is used to see the relation between the effects of its nanostructuring by high-energy ion irradiation (Xe and Kr with energies 26–167 MeV) and the graphene structure. The pore size was found to depend on the domain size and the ion energy, and equal to 10–30 nm and 60–80 nm for domains of 1–3 μm and ~10 μm, respectively. The pore density was estimated as ~10% from the ion fluence. The maximum pore density, approximately equal to the ion dose, was found in the strained graphene blisters. The formation of more complex structural defects (presumably, ultrashort nanotubes covered with a graphene monolayer on the top) is also revealed after the ion irradiation in few-layer graphene. The top layer preservation after irradiation was justified by the molecular dynamics simulation and caused by lower energy losses (absence of the electrons knocked out of the previous layers). The possibility of forming vertical wells in ultrashort nanotubes, due to interlayer covalent bonds at the edges of some pores, is very attractive for applications. The use of CVD graphene provides ample opportunities for controlling the structure and properties of nanostructured materials. © 2022 Elsevier B.V.

Antonova I.V. , Nebogatikova N.A. , Erohin S.V. , Prenas V.A. , Smovzh D.V. , Suprun E.A. , Volodin V.A. , Olejniczak A. , Sorokin P.B.
Nanostructuring of CVD Graphene by High-Energy Heavy Ions
Diamond and Related Materials. 2022. V.123. 108880 :1-11. DOI: 10.1016/j.diamond.2022.108880 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	18 нояб. 2021 г.
Принята к публикации:	30 янв. 2022 г.
Опубликована online:	4 февр. 2022 г.
Опубликована в печати:	1 мар. 2022 г.

Web of science:	WOS:000787859800004
Scopus:	2-s2.0-85124186454
РИНЦ:	48148463
Chemical Abstracts:	2022:354211
Chemical Abstracts (print):	178:306144
OpenAlex:	W4210640691

БД	Цитирований
Scopus	4
РИНЦ	4
Web of science	4
OpenAlex	5