High-Quality Graphene Using Boudouard Reaction | Sciact - CRIS-system of Boreskov Institute of Catalysis

High-Quality Graphene Using Boudouard Reaction Full article

Journal

Advanced Science
, E-ISSN: 2198-3844

Output data

Year: 2022, Volume: 9, Number: 12, Article number : 2200217, Pages count : 12 DOI: 10.1002/advs.202200217

Tags

Boudouard reaction; carbon monoxide; chemical vapor deposition; copper; graphene

Authors

Grebenko Artem K. ^1,2 , Krasnikov Dmitry V. ¹ , Bubis Anton V. ^1,3 , Stolyarov Vasily S. ^2,4,6 , Vyalikh Denis V. ^7,8 , Makarova Anna A. ⁹ , Fedorov Alexander ¹⁰ , Aitkulova Aisuluu ¹ , Alekseeva Alena A. ¹ , Gilshtein Evgeniia ^1,11 , Bedran Zakhar ² , Shmakov Alexander N. ¹² , Alyabyeva Liudmila ² , Mozhchil Rais N. ^3,13 , Ionov Andrey M. ^3,5 , Gorshunov Boris P. ² , Laasonen Kari ¹⁴ , Podzorov Vitaly ¹⁵ , Nasibulin Albert G. ^1,14

Affiliations

1	Skolkovo Institute of Science and Technology, Nobel str. 3, Moscow, 121205, Russia
2	Moscow Institute of Physics and Technology, Institute Lane 9, Dolgoprudny, Russia
3	Insitute of Solid State Physics (RAS), Academician Ossupyan str. 2, Chernogolovka, Russia
4	Dukhov Research Institute of Automatics (VNIIA), Moscow, 127055, Russia
5	HSE University, Myasnitskaya 20, Moscow, 101000, Russian Federation
6	National University of Science and Technology MISIS, Moscow, 119049, Russian Federation
7	Donostia International Physics Center (DIPC), Donostia-San Sebastián, 20018, Spain
8	IKERBASQUE, Basque Foundation for Science, Bilbao, 48011, Spain
9	Physikalische Chemie, Institut für Chemie und Biochemie, Freie Universität Berlin, Arnimallee 22, Berlin, 14195, Germany
10	IFW Dresden, POB 270116, Dresden, D-01171, Germany
11	Empa, Swiss Federal Laboratories for Materials Science and Technology, Ueberlandstrasse 129, Duebendorf, 8600, Switzerland
12	Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090, Russian Federation
13	National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), Moscow, 115409, Russian Federation
14	Aalto University, P.O. Box 16100, Aalto, FI-00076, Finland
15	Department of Physics, Rutgers University, Piscataway, NJ 08854, United States

Funding (8)

1	Ministry of Science and Higher Education of the Russian Federation	0239-2021-0002
2	Federal Ministry of Education and Research	05K19KER
3	Russian Foundation for Basic Research	19-32-90143 (АААА-А20-120063090039-1)
4	Russian Science Foundation	21-19-00226 (121070800201-6)
5	Russian Science Foundation	21-72-20050 (121120700230-9)
6	Russian Science Foundation	21-72-30026 (121040900094-6)
7	Ministry of Science and Higher Education of the Russian Federation	FSMG-2021-0005
8	Council for Grants of the President of the Russian Federation	НШ-1330.2022.1.3

Following the game-changing high-pressure CO (HiPco) process that established the first facile route toward large-scale production of single-walled carbon nanotubes, CO synthesis of cm-sized graphene crystals of ultra-high purity grown during tens of minutes is proposed. The Boudouard reaction serves for the first time to produce individual monolayer structures on the surface of a metal catalyst, thereby providing a chemical vapor deposition technique free from molecular and atomic hydrogen as well as vacuum conditions. This approach facilitates inhibition of the graphene nucleation from the CO/CO2 mixture and maintains a high growth rate of graphene seeds reaching large-scale monocrystals. Unique features of the Boudouard reaction coupled with CO-driven catalyst engineering ensure not only suppression of the second layer growth but also provide a simple and reliable technique for surface cleaning. Aside from being a novel carbon source, carbon monoxide ensures peculiar modification of catalyst and in general opens avenues for breakthrough graphene-catalyst composite production. © 2022 The Authors. Advanced Science published by Wiley-VCH GmbH

Grebenko A.K. , Krasnikov D.V. , Bubis A.V. , Stolyarov V.S. , Vyalikh D.V. , Makarova A.A. , Fedorov A. , Aitkulova A. , Alekseeva A.A. , Gilshtein E. , Bedran Z. , Shmakov A.N. , Alyabyeva L. , Mozhchil R.N. , Ionov A.M. , Gorshunov B.P. , Laasonen K. , Podzorov V. , Nasibulin A.G.
High-Quality Graphene Using Boudouard Reaction
Advanced Science. 2022. V.9. N12. 2200217 :1-12. DOI: 10.1002/advs.202200217 WOS Scopus РИНЦ AN PMID OpenAlex

Submitted:	Jan 19, 2022
Accepted:	Jan 29, 2022
Published online:	Feb 20, 2022
Published print:	Apr 25, 2022

Web of science:	WOS:000758918600001
Scopus:	2-s2.0-85124839935
Elibrary:	48150858
Chemical Abstracts:	2022:1051195
PMID:	35187847
OpenAlex:	W4213127421

DB	Citing
Scopus	21
Web of science	20
Elibrary	16
OpenAlex	26