Catalytic Properties of M-Cu/ZrO2 (M = Fe, Co, Ni) in Steam Reforming of Ethanol | Sciact - CRIS-система Института катализа

Catalytic Properties of M-Cu/ZrO2 (M = Fe, Co, Ni) in Steam Reforming of Ethanol Научная публикация

Журнал

Theoretical and Experimental Chemistry
ISSN: 0040-5760 , E-ISSN: 1573-935X

Вых. Данные

Год: 2013, Том: 48, Номер: 6, Страницы: 386-393 Страниц : 8 DOI: 10.1007/s11237-013-9286-x

Ключевые слова

bimetallic catalysts, cobalt, copper, ethanol, iron, nickel, steam reforming, zirconium dioxide

Авторы

Deinega I.V. ¹ , Dolgykh L.Yu. ¹ , Stolyarchuk I.L. ¹ , Staraya L.A. ¹ , Strizhak P.E. ¹ , Moroz E.M. ² , Pakharukova V.P. ² , Zyuzin D.A. ²

Организации

1	L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv 03028, Ukraine
2	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Prospekt Akademika Lavrent’eva, 5, Novosibirsk 630090, Russian Federation

We show that bicomponent supported catalysts M-Cu/ZrO2 (M = Fe, Co, Ni) are considerably more efficient than Cu/ZrO2 in steam reforming of ethanol at 350-550 °C. We have found that Fe-Cu/ZrO2 has increased activity and selectivity in ethanol steam reforming, due to the presence of highly dispersed copper particles and iron oxide particles, which are active in the water-gas shift reaction, and as a result carbon monoxide (a secondary product of ethanol steam reforming) is converted to the target CO2 and H2.

Deinega I.V. , Dolgykh L.Y. , Stolyarchuk I.L. , Staraya L.A. , Strizhak P.E. , Moroz E.M. , Pakharukova V.P. , Zyuzin D.A.
Catalytic Properties of M-Cu/ZrO2 (M = Fe, Co, Ni) in Steam Reforming of Ethanol
Theoretical and Experimental Chemistry. 2013. V.48. N6. P.386-393. DOI: 10.1007/s11237-013-9286-x WOS Scopus РИНЦ CAPlusCA OpenAlex

Дейнега И.В. , Долгих Л.Ю. , Столярчук И.Л. , Старая Л.А. , Стрижак П.Е. , Мороз Э.М. , Пахарукова В.П. , Зюзин Д.А.
Каталитические свойства М-Сu/ZrO2 (M=Fe,Co,Ni) в процессе парового риформинга этанола
Теоретическая и экспериментальная химия. 2012. Т.48. №6. С.364-371. РИНЦ

Поступила в редакцию:	28 нояб. 2012 г.
Опубликована в печати:	1 янв. 2013 г.
Опубликована online:	27 февр. 2013 г.

Web of science:	WOS:000316017300006
Scopus:	2-s2.0-84880697990
РИНЦ:	20445900
Chemical Abstracts:	2013:346467
Chemical Abstracts (print):	159:10759
OpenAlex:	W1976846000

БД	Цитирований
Web of science	9
Scopus	8
РИНЦ	6
OpenAlex	5