Structure-Guided Insights into non-Catalytic (α-hydroxy)alkylation of Olefins with Alcohols Full article
| Journal |
New Journal of Chemistry
ISSN: 1144-0546 , E-ISSN: 1369-9261 |
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| Output data | Year: 2022, Volume: 46, Number: 20, Pages: 9775-9784 Pages count : 10 DOI: 10.1039/D2NJ00155A | ||
| Tags | Coagulation; Gels; Growth kinetics; Light transmission; Morphology; Optical data storage; Optical microscopy; Particle size; Polymerization; Precipitation (chemical); Size distribution | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0003 |
Abstract:
New pairs of "olefin–alcohol" were involved into the non-catalytic (α-hydroxy)alkylation process at 350 °C – the addition reaction of MeOH, EtOH or 2-PrOH to styrene, cyclohexene, 1-heptene, and limonene to produce carbon-chain elongated alcohols. The contribution of different side reactions (transfer hydrogenation, alcohol dehydration,
C-alkoxylation, etc.) was described for the first time, and the chemo- and regio-selectivity was evaluated for each pair. As a proof-of-concept, the ability of olefinic precursor to participate in two-step elimination–(α-hydroxy)alkylation tandem reaction with alcohol was confirmed: isobutylene generated in situ from tert-butanol at 350 °C reacted with MeOH to give two isomeric alcohols (isoamyl and neopentyl ones) with 34% selectivity.
Cite:
Chibiryaev A.M.
Structure-Guided Insights into non-Catalytic (α-hydroxy)alkylation of Olefins with Alcohols
New Journal of Chemistry. 2022. V.46. N20. P.9775-9784. DOI: 10.1039/D2NJ00155A WOS Scopus РИНЦ ANCAN OpenAlex
Structure-Guided Insights into non-Catalytic (α-hydroxy)alkylation of Olefins with Alcohols
New Journal of Chemistry. 2022. V.46. N20. P.9775-9784. DOI: 10.1039/D2NJ00155A WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jan 11, 2022 |
| Accepted: | Apr 14, 2022 |
| Published online: | Apr 18, 2022 |
| Published print: | May 24, 2022 |
Identifiers:
| Web of science: | WOS:000792323500001 |
| Scopus: | 2-s2.0-85131463203 |
| Elibrary: | 48720658 |
| Chemical Abstracts: | 2022:1226666 |
| Chemical Abstracts (print): | 180:268101 |
| OpenAlex: | W4226051537 |