Реферат: The effect of Si incorporation at the stage of alumina preparation on physico-chemical properties and catalytic performance of NiMo/Al2O3 catalysts for FCC feedstock pretreatment has been studied. Silicon was added to alumina support by kneading. Si/Al molar ratio was 0–0.16. Supports and catalysts were characterized by XRD, MAS NMR spectroscopy, Raman and IR spectroscopies, nitrogen adsorption-desorption, HRTEM, UV-Vis DRS, XPS. Introduction of Si changes textural characteristics of supports and leads to the decrease in acidity of parent alumina caused by blocking of a part of surface OH groups by deposits of silicon compounds. Silicon addition promotes the formation of small amount of strong LAS and strong BAS. Incorporation of Si facilitates segregation of Ni from the NiMoS phase. Testing of catalysts in VGO hydrotreating shows that addition of silicon to alumina support by kneading improves hydrodesulfurization activity of catalysts. However, an improvement in HDN activity was not achieved.

Библиографическая ссылка: Romanova T.S. , Nadeina K.A. , Danilova I.G. , Danilevich V.V. , Pakharukova V.P. , Gabrienko A.A. , Glazneva T.S. , Gerasimov E.Y. , Prosvirin I.P. , Vatutina Y.V. , Kazakov M.O. , Klimov O.V. , Noskov A.S.
Modification of HDT Catalysts of FCC Feedstock by Adding Silica to the Kneading Paste of Alumina Support: Advantages and Disadvantages
Fuel. 2022. V.324. NPart A. 124555 :1-11. DOI: 10.1016/j.fuel.2022.124555 WOS Scopus РИНЦ CAPlus OpenAlex

Даты:

Поступила в редакцию:	30 мар. 2022 г.
Принята к публикации:	7 мая 2022 г.
Опубликована online:	17 мая 2022 г.
Опубликована в печати:	15 сент. 2022 г.

Идентификаторы БД:

Web of science:	WOS:000892006000004
Scopus:	2-s2.0-85130173951
РИНЦ:	48584079
Chemical Abstracts:	2022:1317962
OpenAlex:	W4280584972

Цитирование в БД:

БД	Цитирований
Scopus	12
РИНЦ	10
Web of science	11
OpenAlex	11

Альметрики: