Selective Dimerization of Ethene to 2-Butene on Zn2+-Modified ZSM-5 Zeolite | Sciact - CRIS-система Института катализа

Selective Dimerization of Ethene to 2-Butene on Zn2+-Modified ZSM-5 Zeolite Научная публикация

Журнал

The Journal of Physical Chemistry C
ISSN: 1932-7447 , E-ISSN: 1932-7455

Вых. Данные

Год: 2022, Том: 126, Номер: 15, Страницы: 6570–6577 Страниц : 8 DOI: 10.1021/acs.jpcc.2c01101

Ключевые слова

Butenes; Density functional theory; Dimerization; Fourier transform infrared spectroscopy; Zeolites

Авторы

Lashchinskaya Zoya N. ¹ , Gabrienko Anton A. ¹ , Kolganov Alexander A. ¹ , Pidko Evgeny A. ² , Stepanov Alexander G. ¹

Организации

1	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia
2	Inorganic Systems Engineering Group, Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of Technology, Delft 2629 HZ, The Netherlands

Информация о финансировании (2)

1	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	0239-2021-0003
2	Российский научный фонд	21-73-10013

Selective dimerization of ethene to 2-butene on Zn2+-containing ZSM-5 zeolite (Zn2+/ZSM-5) at 296–523 K has been discovered. The intermediate but-3-en-1-ylzinc species is identified with 13C CP/MAS NMR and Fourier transform infrared spectroscopy. The density functional theory study of two alternative dimerization pathways reveals that the intermediate is formed with the involvement of the saturated bridged dimeric Zn–(CH2)4–O species. It is also shown that ethene conversion to 2-butene increases with the increase in the quantity of Brønsted acid sites in Zn2+/ZSM-5 zeolite; however, the selectivity of the reaction decreases. The results obtained are of potential interest for developing industrially relevant Zn-containing zeolite catalysts for the selective conversion of ethene to 2-butene.

Lashchinskaya Z.N. , Gabrienko A.A. , Kolganov A.A. , Pidko E.A. , Stepanov A.G.
Selective Dimerization of Ethene to 2-Butene on Zn2+-Modified ZSM-5 Zeolite
The Journal of Physical Chemistry C. 2022. V.126. N15. P.6570–6577. DOI: 10.1021/acs.jpcc.2c01101 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	15 февр. 2022 г.
Принята к публикации:	25 мар. 2022 г.
Опубликована online:	6 апр. 2022 г.
Опубликована в печати:	21 апр. 2022 г.

Web of science:	WOS:000793809600004
Scopus:	2-s2.0-85128512818
РИНЦ:	48430683
Chemical Abstracts:	2022:896141
Chemical Abstracts (print):	180:142786
OpenAlex:	W4226352523

БД	Цитирований
Scopus	8
РИНЦ	8
Web of science	8
OpenAlex	8