Role of Brønsted Surface Acid Sites of B2O3–Al2O3 Catalyst Supports in Perylene Radical Cation Formation Studied by Probe EPR with TEMPO Radicals Научная публикация
| Журнал |
The Journal of Physical Chemistry C
ISSN: 1932-7447 , E-ISSN: 1932-7455 |
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| Вых. Данные | Год: 2022, Том: 126, Номер: 4, Страницы: 1809-1816 Страниц : 8 DOI: 10.1021/acs.jpcc.1c09670 | ||
| Ключевые слова | Alumina; Aluminum oxide; Electron spin resonance spectroscopy; III-V semiconductors; Polycyclic aromatic hydrocarbons; Positive ions | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | 0239-2021-0006 |
Реферат:
For the series of borate-modified alumina samples with a wide range of B2O3 content (0–30 wt %), the regularities of the change in acid properties were studied by probe EPR spectroscopy of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and solid-state 1H NMR. An increase in the concentration of Brønsted acid sites (BAS) in the series with an increase in the boron oxide content to 30 wt % was found. The obtained dependences of the BAS concentration for the samples determined from TEMPO adsorption and 1H MAS NMR data are in good agreement. Also, the results of determining the BAS concentration by a direct method (via the concentration of TEMPO complexes with BAS) are close in values to the concentration of perylene radical cations determined on the surface of the corresponding B2O3–Al2O3 samples. The obtained results show that the proposed EPR approaches are promising for the quantitative analysis of surface BAS in the study of various porous acid solids.
Библиографическая ссылка:
Yurpalov V.L.
, Drozdov V.A.
, Karpova T.R.
, Lavrenov A.V.
, Nepomnyashchii A.A.
, Buluchevskiy E.A.
Role of Brønsted Surface Acid Sites of B2O3–Al2O3 Catalyst Supports in Perylene Radical Cation Formation Studied by Probe EPR with TEMPO Radicals
The Journal of Physical Chemistry C. 2022. V.126. N4. P.1809-1816. DOI: 10.1021/acs.jpcc.1c09670 WOS Scopus РИНЦ CAPlus OpenAlex
Role of Brønsted Surface Acid Sites of B2O3–Al2O3 Catalyst Supports in Perylene Radical Cation Formation Studied by Probe EPR with TEMPO Radicals
The Journal of Physical Chemistry C. 2022. V.126. N4. P.1809-1816. DOI: 10.1021/acs.jpcc.1c09670 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
| Поступила в редакцию: | 9 нояб. 2021 г. |
| Принята к публикации: | 11 янв. 2022 г. |
| Опубликована online: | 19 янв. 2022 г. |
| Опубликована в печати: | 3 февр. 2022 г. |
Идентификаторы БД:
| Web of science: | WOS:000745835700001 |
| Scopus: | 2-s2.0-85123943364 |
| РИНЦ: | 48147627 |
| Chemical Abstracts: | 2022:168871 |
| OpenAlex: | W4205337386 |