Cyclization of Acetylenic Derivatives of Aromatic Carboxylic Acids | Sciact - CRIS-system of Boreskov Institute of Catalysis

Cyclization of Acetylenic Derivatives of Aromatic Carboxylic Acids Full article

Journal

Bulletin of the Russian Academy of Sciences, Division of chemical science
ISSN: 1063-5211

Output data

Year: 1992, Volume: 41, Pages: 1672–1679 Pages count : 8 DOI: 10.1007/BF00863591

Tags

l-phenylethynylanthraquinone-2-carboxylic acid, 1-hexyn-l-yl-anthraquinone-2-carboxylic acid, l- (3-phenoxypropyn-l-yl)anthraquinone-2-carboxylic acid, intramolecular cyclization, MNDO calculation method.

Authors

Ivanchikova I.D. , Usubalieva G.É. , Schastnev P.V. , Moroz A.A. , Shvartsberg M.S.

Affiliations

1	Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, 630090 Ntwosibirsk
2	Novosibirsk State University

The Cu(I)-catalyzed intramolecular cyclization of 1-phenylethynyl-and 1-hexyn-1-yl-anthraquinone-2-carboxylic acid is a 6-endo-dig-addition, whereas the reaction for 1-(3-phenoxypropyn-1-yl)anthraquinone-2-carboxylic acid proceeds in a directionally nonspecific way. It is shown that the cyclization of vicinal acetylenic derivatives of aromatic carboxylic acids leads to the formation of the more stable of the possible cyclic structures.

Ivanchikova I.D. , Usubalieva G.É. , Schastnev P.V. , Moroz A.A. , Shvartsberg M.S.
Cyclization of Acetylenic Derivatives of Aromatic Carboxylic Acids
Bulletin of the Russian Academy of Sciences, Division of chemical science. 1992. V.41. P.1672–1679. DOI: 10.1007/BF00863591 Scopus РИНЦ OpenAlex

Иванчикова И.Д. , Усубалиева Г.Э. , Счастнев П.В. , Мороз А.А. , Шварцберг М.С.
Циклизация ацетиленовых производных ароматических карбоновых кислот
Известия Академии наук СССР. Серия химическая (с 1991 г. Известия Академии наук. Серия химическая). 1992. №9. С.2138-2146.

Submitted:	Sep 14, 1991
Published print:	Sep 1, 1992

Scopus:	2-s2.0-34249830694
Elibrary:	48487615
OpenAlex:	W2089329394

DB	Citing
Scopus	4
OpenAlex	5