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Immobilization of Polyoxometalates on Carbon Nanotubes: Tuning Catalyst Activity, Selectivity and Stability in H2O2-Based Oxidations Научная публикация

Журнал Catalysts
ISSN: 2073-4344
Вых. Данные Год: 2022, Том: 12, Номер: 5, Номер статьи : 472, Страниц : 24 DOI: 10.3390/catal12050472
Ключевые слова heterogeneous catalysis; hydrogen peroxide; liquid-phase selective oxidation; polyoxometalates; carbon nanotubes; N-doping; supported catalysts
Авторы Evtushok Vasilii Yu. 1,2 , Lopatkin Vladimir A. 1,2 , Podyacheva Olga Yu. 1 , Kholdeeva Oxana A. 1
Организации
1 Boreskov Institute of Catalysis, Lavrentieva Ave. 5, 630090 Novosibirsk, Russia
2 Novosibirsk State University, Pirogova Str. 2, 630090 Novosibirsk, Russia

Информация о финансировании (1)

1 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) 0239-2021-0009

Реферат: In recent years, carbon nanotubes (CNTs), including N-doped ones (N-CNTs), have received significant attention as supports for the construction of heterogeneous catalysts. In this work, we summarize our progress in the application of (N)-CNTs for immobilization of anionic metal-oxygen clusters or polyoxometalates (POMs) and use of (N)-CNTs-supported POM as catalysts for liquid-phase selective oxidation of organic compounds with the green oxidant–aqueous hydrogen peroxide. We discuss here the main factors, which favor adsorption of POMs on (N)-CNTs and ensure a quasi-molecular dispersion of POM on the surface and their strong attachment to the support. The effects of the POM nature, N-doping of CNTs, acid additives, and other factors on the POM immobilization process and catalytic activity/selectivity of the (N)-CNTs-immobilized POMs are analyzed. Particular attention is drawn to the critical issue of the catalyst stability and reusability. The scope and limitations of the POM/(N)-CNTs catalysts in H2O2-based selective oxidations are discussed
Библиографическая ссылка: Evtushok V.Y. , Lopatkin V.A. , Podyacheva O.Y. , Kholdeeva O.A.
Immobilization of Polyoxometalates on Carbon Nanotubes: Tuning Catalyst Activity, Selectivity and Stability in H2O2-Based Oxidations
Catalysts. 2022. V.12. N5. 472 :1-24. DOI: 10.3390/catal12050472 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 23 мар. 2022 г.
Принята к публикации: 20 апр. 2022 г.
Опубликована online: 22 апр. 2022 г.
Опубликована в печати: 1 мая 2022 г.
Идентификаторы БД:
Web of science: WOS:000801493500001
Scopus: 2-s2.0-85130439353
РИНЦ: 48591232
Chemical Abstracts: 2022:1436045
OpenAlex: W4224316704
Цитирование в БД:
БД Цитирований
РИНЦ 7
Scopus 10
Web of science 8
OpenAlex 9
Альметрики: