Synthesis, Luminescent and Magnetic Properties of New Tetranuclear Lanthanide Complexes with 4-hydroxy-2,1,3-benzothiadiazolate and Dibenzoylmethanide Ligands | Sciact - CRIS-система Института катализа

Synthesis, Luminescent and Magnetic Properties of New Tetranuclear Lanthanide Complexes with 4-hydroxy-2,1,3-benzothiadiazolate and Dibenzoylmethanide Ligands Научная публикация

Журнал

Polyhedron
ISSN: 0277-5387

Вых. Данные

Год: 2017, Том: 124, Страницы: 139-144 Страниц : 6 DOI: 10.1016/j.poly.2016.12.041

Ключевые слова

Benzothiadiazole; Coordination compound; Infrared luminescence; Lanthanide; Magnetic properties

Авторы

Sukhikh T.S. ^1,2 , Bashirov D.A. ^1,2 , Kolybalov D.S. ² , Andreeva A.Y. ¹ , Smolentsev A.I. ¹ , Kuratieva N.V. ^1,2 , Burilov V.A. ³ , Mustafina A.R. ⁴ , Kozlova S.G. ^1,2 , Konchenko S.N. ^1,2

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090 Novosibirsk, Russia
2	Department of Natural Sciences, National Research University – Novosibirsk State University, 630090 Novosibirsk, Russia
3	Butlerov Institute of Chemistry, Kazan Federal University, 420008 Kazan, Russia
4	Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, 420088 Kazan, Russia

Four new tetranuclear complexes, [Ln4(dbm)4(O-btd)6(OH)2] 1a (Ln = Yb), 1b (Ln = Dy) and [Ln4(dbm)6(O-btd)4(OH)2] 2a (Ln = Yb), 2b (Ln = Dy) (O-btd = 4-hydroxo-2,1,3-benzothiadiazolate and dbm = dibenzoylmethanide), and their solvates with toluene and tetrahydrofuran were synthesized. The magnetic properties of the complexes 1a, 1b, 2a and 2b have been studied, revealing different magnetic susceptibility patterns for the Yb(III) and Dy(III) complexes in the temperature range 80–300 K. Upon lowering the temperature, a weak antiferromagnetic ordering is observed for both Yb compounds, while the Dy derivatives are assumed to show weak ferromagnetic interactions. The Yb complexes 1a and 2a demonstrate strong NIR luminescence at ∼1000 nm in CH2Cl2 solution upon excitation of the (O-btd)− ligand. This observation suggests the (O-btd)− ligand to be an efficient antenna ligand for lanthanide-based NIR luminescence.

Sukhikh T.S. , Bashirov D.A. , Kolybalov D.S. , Andreeva A.Y. , Smolentsev A.I. , Kuratieva N.V. , Burilov V.A. , Mustafina A.R. , Kozlova S.G. , Konchenko S.N.
Synthesis, Luminescent and Magnetic Properties of New Tetranuclear Lanthanide Complexes with 4-hydroxy-2,1,3-benzothiadiazolate and Dibenzoylmethanide Ligands
Polyhedron. 2017. V.124. P.139-144. DOI: 10.1016/j.poly.2016.12.041 WOS Scopus OpenAlex CAPlusCA

Поступила в редакцию:	25 окт. 2016 г.
Принята к публикации:	18 дек. 2016 г.
Опубликована online:	5 янв. 2017 г.
Опубликована в печати:	9 мар. 2017 г.

≡ Web of science:	WOS:000397834900016
≡ Scopus:	2-s2.0-85009496029
≡ OpenAlex:	W2568618859
≡ Chemical Abstracts:	2017:86181
≡ Chemical Abstracts (print):	166:215676

≡ Scopus	15	Сбор данных от 15.02.2026
≡ Web of science	14	Сбор данных от 20.02.2026
≡ OpenAlex	14	Сбор данных от 15.02.2026