Ni(Co)-Containing Catalysts Based on Perovskite-Like Ferrites for Steam Reforming of Ethanol Full article
| Journal |
Catalysis for Sustainable Energy
ISSN: 2084-6819 |
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| Output data | Year: 2014, Volume: 2, Number: 1, Pages: 10-20 Pages count : 11 DOI: 10.2478/cse-2014-0002 | ||||||
| Tags | Ethanol steam reforming, nickel, cobalt, praseodimium ferrite, molybdenum | ||||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Siberian Branch of the Russian Academy of Sciences | 8 |
| 2 | Russian Foundation for Basic Research | 12-03-93115 |
| 3 | The Ministry of Education and Science of the Russian Federation |
Abstract:
For two series of catalysts based on praseodymium ferrite, their structural and redox properties as well as performance in ethanol steam reforming have been studied. The first series was PrFe1-xNi(Co)xO3 (x=0.3-0.4) perovskites prepared by modified Pechini route, and the second one was 5%wt.Ni(Co)/PrFeO3 of different dispersion prepared by impregnation of PrFeO3, including samples modified by 5%wt. Mo. At temperatures above 700°C, for all catalysts, the main products were hydrogen and CO. At temperatures below 700°C, initial ethanol conversion and hydrogen yield were higher for supported catalysts as compared with ones derived from Ni(Co)-containing perovskites. While Ni-based catalysts derived from perovskite were more active as compared with Co-based samples, Co-supported PrFeO3 perovskite has shown a higher initial activity as compared with Ni-supported one. The long-term tests in the realistic feed and TEM studies of spent catalysts revealed that perovskite-derived catalysts have a higher coking stability than perovskite-supported ones due to formation of highly dispersed Ni-Fe alloy particles strongly interacting with disordered perovskite–like matrix. The method of Mo supporting only slightly affects the initial activity of Ni/PrFeO3–based catalysts but noticeably modifies their coking stability: 5%Mo/5%Ni/PrFeO3 catalyst prepared by successive impregnation possesses the highest stability among perovskite-supported catalysts.
Cite:
Arapova M.V.
, Pavlova S.N.
, Rogov V.A.
, Krieger T.A.
, Ishchenko A.V.
, Roger A.-C.
Ni(Co)-Containing Catalysts Based on Perovskite-Like Ferrites for Steam Reforming of Ethanol
Catalysis for Sustainable Energy. 2014.
V.2. N1. P.10-20. DOI: 10.2478/cse-2014-0002
РИНЦ
AN
OpenAlex
Ni(Co)-Containing Catalysts Based on Perovskite-Like Ferrites for Steam Reforming of Ethanol
Catalysis for Sustainable Energy. 2014.
V.2. N1. P.10-20. DOI: 10.2478/cse-2014-0002
РИНЦ
AN
OpenAlex
Files:
Full text from publisher
Dates:
| Submitted: | Oct 16, 2013 |
| Accepted: | Dec 9, 2013 |
| Published print: | Jan 24, 2014 |
| Published online: | Feb 24, 2014 |
Identifiers:
| Elibrary: | 30705975 |
| Chemical Abstracts: | 2015:611943 |
| OpenAlex: | W2074817178 |