High-Loaded Ni-Based Catalysts Obtained via Supercritical Antisolvent Coprecipitation in Transfer Hydrogenation of Anisole: Influence of the Support Full article
| Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
||
|---|---|---|---|
| Output data | Year: 2022, Volume: 643, Article number : 118792, Pages count : 10 DOI: 10.1016/j.apcata.2022.118792 | ||
| Tags | Transfer hydrogenation; Supercritical antisolvent precipitation; Anisole; Ni-based catalystsl Supercritical; 2-PrOH | ||
| Authors |
|
||
| Affiliations |
|
Funding (1)
| 1 | Russian Science Foundation | 21-13-00065 |
Abstract:
Transfer hydrogenation of anisole in 2-PrOH has been studied as a model reaction for lignocellulose processing. The reaction was studied over high-loaded Ni-based catalysts synthesized via supercritical antisolvent precipitation of a Ni precursor and sols of four oxides: Al2O3, SiO2, TiO2, and ZrO2. It was demonstrated that the oxide support significantly affects the structure of the catalysts, their activity, and selectivity. The best performance in the transfer hydrodeoxygenation of anisole was shown by Ni supported on alumina at 250 °C, which was explained by the highest dispersion of Ni0 particles in this catalyst and by the highest concentration of acid centers.
Cite:
Philippov A.A.
, Nesterov N.N.
, Pakharukova V.P.
, Martyanov O.N.
High-Loaded Ni-Based Catalysts Obtained via Supercritical Antisolvent Coprecipitation in Transfer Hydrogenation of Anisole: Influence of the Support
Applied Catalysis A: General. 2022. V.643. 118792 :1-10. DOI: 10.1016/j.apcata.2022.118792 WOS Scopus РИНЦ OpenAlex ANCAN
High-Loaded Ni-Based Catalysts Obtained via Supercritical Antisolvent Coprecipitation in Transfer Hydrogenation of Anisole: Influence of the Support
Applied Catalysis A: General. 2022. V.643. 118792 :1-10. DOI: 10.1016/j.apcata.2022.118792 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | May 9, 2022 |
| Accepted: | Jul 19, 2022 |
| Published online: | Jul 20, 2022 |
| Published print: | Aug 5, 2022 |
Identifiers:
| ≡ Web of science: | WOS:000844593700002 |
| ≡ Scopus: | 2-s2.0-85134843365 |
| ≡ Elibrary: | 50361383 |
| ≡ OpenAlex: | W4286266659 |
| ≡ Chemical Abstracts: | 2022:1954266 |
| ≡ Chemical Abstracts (print): | 179:330659 |